有机化学期末复习总结(上学期).pptVIP

硼氢化反应的机理 CH3CH=CH2 + H-BH2 B2H6 亲电加成 CH3CH—CH2 H—BH2 … … ??- ?+ ?- CH3CH—CH2 H BH2 … … … … CH3CH2CH2BH2 硼接近空阻小、?电荷密度高的双键碳，并接纳?电子 负氢与正碳互相吸引 四中心过渡态 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 烷基硼氧化反应的机理 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 烷基硼还原反应的机理 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 反应机理： Na + NH3 Na+ + （e-) NH3 CH3OH -CH3O- (e-) NH3 CH3OH 自由基