N-杂环卡宾钯催化剂.docxVIP

2010年，Michael G. Gardiner 和他的同事合成了新型的氮杂环卡宾化合物，A colorless solution of 1 over anhydrous Na2CO3 in dry MeOH was heated at 508C for two hours to give a red solution, from which red crystals of 2 were obtained in 84%yield after filtration and concentration (Scheme 1).[8] Complex 2 has high stability as a solid (more than one year) and in MeOH and THF (several months). The complex is tolerant to moisture, but reacts quickly with atmospheric oxygen in solution and the solid state.Peter D. W. Boyd, Alison J. Edwards, Michael G. Gardiner, Angew. Chem. Int. Ed. 2010, 49, 6315 –6318.2008年，Takeshi Makino