3.0第3专题.pptVIP

【演练2】已知: ①C(s)+?O2(g)? CO(g) ΔH=-110.5 kJ·mol-1 ②C(s)+O2(g)? CO2(g) ΔH=-393.51 kJ·mol-1 则反应C(s)+CO2(g)? 2CO(g)的ΔH为?(　????) A.-283.01 kJ·mol-1　　B.+172.51 kJ·mol-1 C.+283.1 kJ·mol-1　　D.+504.00 kJ·mol-1 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 【解析】根据盖斯定律,将②式等式左右两边对调得CO2(g)? C(s)+O2(g)　ΔH=+393.51 kJ·mol-1,①式×2得2C(s)+O2(g)? 2CO(g) ΔH=-110.5×2 kJ·mol-1,二式相加合并得C(s)+CO2(g)? 2CO(g) ΔH=+393.51 kJ·mol-1-221 kJ·mol-1=+172.51 kJ·mol-1。 【