二氧化钛 纳米管阵列课件.pptVIP

多元钛基合金氧化物纳米管制备和光催化性能研究进展 Background TiO2纳米管的修饰 noble metal deposition narrow band-gap semiconductors coupling dye sensitization 后修饰 多元宏观结构上的简单叠加与复合，组分分布不均匀 与TiO2纳米管作用不强，易于从本体脱落 降低TiO2纳米管本身固有的比表面积 原位修饰 钛合金纳米管 only absorb the UV light sluggish charge transfer kinetics narrowing band gap aligning the band-edge positions maximizing the surface area using charge transfer catalysts strongly enhanced water splitting ability（undoped TiO2 nanotube） long-term stability (many other doping attempts) more efficient than pure TiO2 nanotubes decorated with RuO2 nanoparticles TOF-SIMS是通过用一次离子激发样品表面，打出极其微量的二次离子，根据二次离子因不同的质量而飞行到探测器的时间不同来测定离子质量的极高分辨率的测量技术 0.01 at% 0.05 at% 0.1 at% 0.2 at% 0.5 at% 1.2 at% 0.25% 0.95% AM 1.5 solar simulator 0.05 at% Ru-alloy layers at 500 mV applied bias MoO3 in Self-Organized TiO2 Nanotubes for Enhanced Photocatalytic Activity Patrik Schmuki et al. UV light (325 nm) AO7 Enhanced Photoassisted Water Electrolysis Using Vertically Oriented Anodically Fabricated Ti-Nb-Zr-O Mixed Oxide Nanotube Arrays Nageh K. Allam, Faisal Alamgir, Mostafa A. El-Sayed ACS Nano 2010(4) 10 V 20 V 15 V 20 V 30 V 40 V 甲酰胺溶液 水溶液 7 h 20 h 0.2 M NH4F + 0.1 M H3PO4 Ti4+ Nb5+ Zr4+ 1 M KOH solution under UV (320~400 nm, 100 mW/cm2) why tube length can be used to explain the different photoconversion efficiency of the 4 μ m and 7 μ m long nanotube TiO2 nanotube (7μ m ): 9.7 % Ti-Nb-Zr-O nanotube (7 μ m ): 11.4 % Ti-Nb-Zr-O nanotube (4 μ m ): 6.9 % distinct tube structure distinct tube composition 21 ± 2 nm wall thickness 10 ± 2 nm wall thickness estimated flatband potential Conclusion 利用多元钛基合金制备纳米管阵列可以实现对TiO2-NTs的原位修饰，具有后修饰不可比拟的优势 TOF-SIMS是一种表面分析的有效手段，可以检测表面极微量成分 计算平带电势的方法 计算光转换效率的方法 * *