金属有机化学第十三章.pptVIP

99 24 r.t. CH2Cl2 1 9 96 24 r.t. hexane 1 8 96 24 r.t. Et2O 1 7 97 24 r.t. toluene 1 6 0 24 0 or 60 THF 0 5 66 24 r.t. THF 0.5 4 95 24 r.t. THF 1 3 95 24 r.t. THF 3 2 92 24 r.t. THF 5 1 Yieldb (%) time (h) temp. (?C) solvent Cat. Loading (mol %) entry 92 4-O2NPhNH2 [(Me3Si)2N]3Y 8 93 4-O2NPhNH2 [(Me3Si)2N]3Yb 7 96 PhNH2 [(Me3Si)2N]3Yb 6 99 PhNH2 Ln = La 5 98 PhNH2 Ln = Sm 4 96 PhNH2 Ln = Eu 3 97 PhNH2 Ln = Y 2 96 PhNH2 Ln =Yb 1 yield ArNH2 catalyst entry Plot of Yields of Guanidine versus Reaction Time. The Reaction was performed by treating 1 equiv. of aniline with 1 equiv. of N,