燃料电池原理及传递过程-II-2016讲义.ppt

Fundamental and Transport in Fuel Cells吴雪梅TelEmail：xuemeiw@ * * * * * http://www.amolf.nl/news/news-archive/detailpage/back_to/news-archive/article/water-lends-protons-a-helping-hand//chash/ddde2cfa66/ A process where hydrogen bonds between water molecules are converted into covalent bonds, and vice versa (see figure 1 and animation 1). Thus, it is not the proton itself that is transported; only the charge of the proton is transported; and not its mass. The charge is basically passed on from water molecule to water molecule. * * * * 关联含水量\温度 * * 进一步将外部水活度与膜中的水含量关联 * 超强碱：pKa20 ，Nafion：超强酸性 * 比较氟/非氟 * Nafion高电导率的原因： 非氟膜的差距：离子传导通道的尺寸小，连同性差 * Nafion高电导率的原因： 非氟膜的差距：离子传导通道的尺寸小，连同性差 * * * by SAXS and TEM showed that the copolymers exhibited a bicontinuous morphology with different hydrophilic PSSA domain sizes (7-19 nm based on TEM), which is the similar feature of Nafion. At 90% RH, proton conductivity of PNS-PSSP PEMs increased with decreasing domain size * 说明比无规聚合物更容易做到磺酸基团的集中分布，相分离完全 * * * Fig. 1. SEM micrographs of SPES electrospun nano?bers (a) and cross-sectional area (b) of the TLM at different magni?cations. Fig. 2. schematically representation of designed TLM (c). Fig. 4. Polarization curves (a and c) and power outputs (b and d) of Na?on/SPES nano?ber/Na?on, Na?on112, and Na?on117 using 5 M (b and d) methanol concentrations at 70 ?C. * Fig. 1. Schematic diagrams of A) conductive inorganic ? ber/polymer hybrid membrane, and B) the long-range ionic channel between the conductive ? ber and functional polymer matrix. * * * * 但无溶胀性能的表征 * * * * * * * 关联含水量的不同实验/关联方法 * 加SPEEK图 传递通道的曲折度与水含量相关 缺点： 热稳定性差，酸性较低 优点： 反应简单，适应性广 优点： -SO3H取代位置为带有吸电基的苯环，热稳定性好，酸性较高 缺点： 反应复杂 ① Improving acidity 聚合物主链上接枝脂肪族磺酸； 磺酸的解离程度高于直接与苯环相连。 Improving acidity 磺化较均匀，制备嵌段或无规聚合物，吸电位置磺化 反应温度高、时间长，磺化聚合物的分子量不易控制。 磺酸单体的聚合 Crosslinking, blend, hybrid, difficult to optimize 小分子醇为交联剂 SPPESK的二元胺交联 Overcome brittleness of covalent crosslinking Limited thermal stability ② Acid-base cr