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ProgressofCdTePolycrystallineThinFilmsolarcellsinSichuanUniversity.
Progress of CdTe Polycrystalline Thin Film solar cells in Sichuan University
Jingquan Zhang, Wei Cai, Lianghuan Feng*, Yaping Cai, Bing Li, Lili Wu, Wei Li, Jiagui Zheng
（*Responding author and reporter）
Department of Materials Science, Sichuan University, Chengdu 610064, China
Abstract
In order to decrease further the fabrication cost, two key technologies have been studied. The first is the closed space sublimation (CSS) in Ar+O2 atmosphere. A special CSS procedure of depositing CdTe thin films on smooth glass substrata has been developed. The structural characteristics of CdTe films deposited on both kinds of substrata--glass and CdS films--have been compared, which shows that there are the same structures of CdTe thin films on both kinds of substrata when these films are deposited at the same temperature. The optical and electrical properties of CdTe films on glass substrata are observed, and the effects of post-treatment on the properties are studied. The second is the technology about back contact and back electrode. In general, Au as a metal of high work function is currently used for back electrode of CdTe solar cells. Ni also is a metal of high work function, hence, can be used to substitute for Au. The effects of Au and Ni back electrode on the performance of CdTe solar cells have been investigated. The experimental results show that Ni is better than Au when there is a complex back contact layer between CdTe layer and back electrode. These results have been used to prepared CdS/CdTe/ZnTe:Cu solar cells and modules.
Introduction
To date, about ten methods of fabricating CdTe thin films have been developed [1,2,3], but the highest efficiency records of small-area CdTe cells have been demonstrated just by CSS [4,5,6]. In those papers, CdTe thin films were deposited in O2/He atmosphere. In order to decrease the cost of CdTe thin film cells, we need to substitute Ar for He, and are concerned in development of CSS method in O2/Ar atmosphere. Therefore,
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