高宏定稿-银改性的氧化锡纳米量子点气敏传感器设计及其研究..docVIP

摘要 本课题采用溶胶-凝胶-水热法制备SnO2量子点和Ag改性的SnO2量子点，使用旋转镀膜法镀膜，并研究了改性前后SnO2材料及薄膜的相关特性。采用X射线衍射仪(XRD)对其晶体结构进行了检测，发现Ag离子的加入使得其粒径变大；然后采用紫外-可见分光光度计(UV-Vis)和荧光分光光度计（PL）分析了薄膜的光学性质，发现Ag离子的引入使得SnO2发生红移，带隙变窄；接着用原子力显微镜(AFM)研究了薄膜的表面形貌，薄膜表面比较平整致密。最后以此薄膜为基础，制作了SnO2纳米量子点薄膜气敏传感器并测试了其气敏性能。Ag的引入改善了其对H2S和NO2的气敏性能。 关键词：SnO2 ，量子点，纳米材料，气敏材料，气敏传感器 ABSTRACT In this subject, SnO2 quantum dot and silver-modified SnO2 quantum dots were successfully obtained by sol-gel technology and hydrothermal method .Then we use spin coating method successfully got the coating film.Some related properties of them were studied.The crystal structure of the thin films were studied by X-ray diffraction (XRD),through which we found that the grain diameter became bigger than former for the addition of Ag ions;Then we used ultraviolet-visible spectrophotometer and fluorometry to study their optical properties and discovered the redshift of SnO2 ,which is to say the band gap of the silver-modified SnO2 narrowed down;After that the microstructure of the films was observed by atomic force microscopy(AFM),and the films showed smooth and compact surface; Finally,we made the silver-modified SnO2 quantum dot gas sensors based on these films and studied their gas sensing performance.Ag ions improved their gas sensitivity for H2S and NO2. Key Words: SnO2, Quantum dot,nanometer materials,gas-sensing materials, Gas sensors 目录 第一章 引言 1 1.1选题背景 1 1.2 研究目的和意义 2 1.3 研究思路 2 第二章 研究背景和理论基础 3 2.1 量子点 3 2.2 SnO2量子点简介 9 2.3 溶胶-凝胶法（Sol-Gel法）和水热法简介 11 2.3.1 溶胶-凝胶法简介 11 2.3.2 溶胶-凝胶法原理 12 2.3.3 溶胶-凝胶法基本特点 12 2.3.4 水热法简介 13 2.4 气敏传感器介绍 13 第三章 SnO2样品制备及其结构表征 18 3.1 SnO2量子点的制备 18 3.1.1 实验设备与仪器 18 3.1.2 实验试剂 18 3.1.3实验步骤及方法 19 3.2 SnO2样品结构表征结果分析 20 3.2.1 X射线衍射分析 20 3.2.2薄膜的吸收和透射性能测试 22 3.2.3荧光光谱分析 26 3.2.4 原子力显微镜（AFM）下薄膜表面形貌测试 28 第四章 Ag改性的SnO2气敏传感器气敏性能测试 33 4.2.1 Ag改性的SnO2气敏传感器的I-V曲线 34 4.2.2 Ag改性的SnO2气敏传感器对不同浓度H2S的响应 35 4.2.3 Ag改性的SnO2气敏传感器对不同浓度NO2的响应 39 第五章 结论和展望 43 参考文献 44 致谢 46 外文资料原文 47 外文资料译文 52 第一章 引言 1.1选题