35-36 表面分析仪器.ppt

化学结构分析 依据：原子的化学环境与化学位移之间的关系； 例：化合物中有两种碳原子，两个峰；苯环上碳与羰基上的碳； 羰基碳上电子云密度小，1s电子结合能大（动能小）； 峰强度比符合碳数比。 XPS Analysis of Pigment from Mummy Artwork 150 145 140 135 130 Binding Energy (eV) PbO2 Pb3O4 500 400 300 200 100 0 Binding Energy (eV) O Pb Pb Pb N Ca C Na Cl XPS analysis showed that the pigment used on the mummy wrapping was Pb3O4 rather than Fe2O3 Egyptian Mummy 2nd Century AD World Heritage Museum University of Illinois Analysis of Carbon Fiber- Polymer Composite Material by XPS Woven carbon fiber composite XPS analysis identifies the functional groups present o