附着性和颗粒型膨胀床生物制氢反应器的运行和调控.doc

题 目 附着性和颗粒型膨胀床生物制氢反应器的运行和调控  Through the research of the biofilm-based expanded bed, the results showed organic loading rate (OLR) was a significant parameter in reactor control and hydrogen production, especially in fermentation types formation. Ethanol-type fermentation formed under the OLR of 10 kgCOD/m3·d.The biofilm-based expanded bed reactor performed well in 31d operation,　pH=4.2~4.4 and the average hydrogen production rate was 0.66 L/L·h. Through the research of the granule-based expanded bed, the results showed that hydrogen-producing granule was observed at the 20d from startup, and the maximum hydrogen production rate was 1.07 L/L·h when OLR=86.3 kgCOD/ m3·d. Glucose as substrate，start biofilm-based and granule-based expanded bed hydrogen-producing reactors. The results showed that when HRT of 1.0h, the corresponding glucose concentration of 40g/L, the biofilm-based expanded bed achieved maximum hydrogen production rate of 6.54　L/L·h; when HRT was 1.5 h, the corresponding glucose concentration of 60 g/L, the granule-based expanded bed reactor achieved maximum hydrogen production rate of 6.85　L/L·h.　When HRT of 1.0h and the corresponding glucose concentration of 40 g/L, the two reactors obtained the maximum hydrogen of 1.69mol/mol-glucos and 1.54　mol/mol-glucose,　respectively. 摘 要 能源枯竭、环境恶化是人类正在面临着的严峻挑战。氢气清洁、高，生物制氢技术成为氢能发展的必然趋势。发酵法生物制氢技术产业化的关键因素提高反应器系统的产氢从而降低制氢成本。本文研究了附着型和颗粒型膨胀床反应器的启动和运行调控及其影响因素，并通过各自的产氢效能进行了比较分析。 1．人类经济社会发展[1]。在19世纪便已发现细菌和藻类[2]，但无进一步研究。而20世纪70年代的能源，于是便开始研究生物制氢领域2,3]。生物制氢领域的各种现代生物技术的应用大大推进了生物制氢技术的进一步发展[]。氢能的密度高汽油2.68倍转化为动力热效率高常规石化能源30%～60%[5]氢。 厌氧附着膜膨胀床(Anaerobic Attached microbial Film Expanded Bed, AAFEB)反应器是Jewell等人于20世纪70年代中期研制的厌氧消化工艺。在AAFEB反应器中，，方式进入生物膜废水中的营养成份，在的联合作用下，[10]。厌氧附着膜膨胀床(AAFEB)是一种效率高，适应性广的厌氧处理工艺，现已成功地用于处理不同类型和浓度的有机废水。然而缺乏新型消化器的设计、运行控制参数至今还没有大型AAFEB装置应用于生产[]。 厌氧膨胀颗粒床反应器( Expanded Granular Sludge Bed , EGSB)?反应器由荷兰Wageinge农业大学的Letinga等人于20世纪90年代初研发大部分的研究都集中于处理CODCr的质量浓度低于1000 mg/L的低温低浓度污水[]。低浓度废水通常是指CODCr的