原创力文档Changes in the Electrical Resistivity of Thin-Films for Polymer Composites Induced by Heating-Cooling Cycles.pdf
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Changes in the Electrical Resistivity of Thin-Films for Polymer Composites Induced by Heating-Cooling Cycles.pdf
JournalofMaterialsScienceandEngineeringB2(12)(2012)601—610
… N 菇
ChangesintheElectricalResistivityofThin—FiImSfor
PolymerCompositesInducedbyHeating——Cooling
Cycles
SusanaHemfindezL6pez，EnriqueViguerasSantiago，MiguelMayorgaRojasandDelfinoReyesContreras
． ResearchandDevelopLaboratoryonAdvancesMaterials(LIDMA)ChemistryFacultyAutonomousUniversityofMexicoState
PaseoCol6nesquinaPaseoTollocan．s／n,Toluca,CP．50000,Mdxico
2．SciencesFaculyt,AutonomousUniversiytofMexicoState．AvlnstitutoLiterario100,ColCentro,Toluca,C．P．50004Mdxico
Received：August13，2012／Accepted：September17，2012／Published：December25，2012
Abstract：Thispaperisfocusointheanalysisoftheelectricalresistivityofpolymercompositesrespecttothetemperaturewhen
samplesareunderheating—coolingcyclesintwoytpeofexperimentsnma ely：(1)atthreedifferentheatingratesnad(2)anisothermic
one．ThreedifferentfilmsS1．S2andS3ofPolystyrene+22wt％CBweresubmittedtoseveralheating—coolingcyclesuntilareversing
processoftheresistivitybehaviorwasreachedforeachfilm．Theheatingwasperformedfromroomtemperature，RT(24。C)to120。C
ataratesofI，2and5。C／min，respectively．A fourthfilm S4wasexposedtoisothemr ic-heating-coolingcycles，consistingonheatrfom
RTto120。C(at2。Cm／in)andkeepthefilmat120。Cofr2．5hours．Thecoolingratewas0．2。C／minofrallsamples．Resultsshowthat
thecycle’snumberofrreachingtheelectricalstabiliyt offilmswerestronglydependentontheheatingratemorethanthekindof
process(continuousorisothermic)．Mainanalysisshowsthatasalowertheheatingrate(1。C／min)thenumberofheating-cooling
cyclesforreachingthereversibility(electricalstabiliyt)areless(6cyclesinourcase)thanthoseforhigherheatingrates(9nad12
cycles)．Resultsareexplainedintermsoftheredistributionofcrabonblackparticlesduetothecompositesstructuralandthermal
relaxation；inotherwordsthedynamicpolymerchainmobilityduringtheheatingprocessandthechainrelaxationprocessduringthe
coolingone．
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