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Deflation rate dependence of receding contact angle on polymeric surfaces.pdf
Journal of the Taiwan Institute of Chemical Engineers 61 (2016) 26–31
Contents lists available at ScienceDirect
Journal of the Taiwan Institute of Chemical Engineers
journal homepage: /locate/jtice
De?ation rate dependence of receding contact angle on polymeric surfaces
Tzyy-Shyang Lin a, Yi-Hong Zeng b, Ruey-Yug Tsay c,?, Shi-Yow Lin b,?
a Department of Physics, National Taiwan University, 1 Roosevelt Road, Sec. 4, Taipei 106, Taiwan b Department of Chemical Engineering, National Taiwan University of Science and Technology, 43 Keelung Road, Sec. 4, Taipei 106, Taiwan c Institute of Biomedical Engineering, National Yang-Ming University, 155 Li-Nung St., Sec. 2, Taipei 112, Taiwan
article info
Article history: Received 4 October 2015 Revised 21 November 2015 Accepted 7 December 2015 Available online 14 January 2016
Keywords: Receding contact angle Sessile drop method Contact line velocity Dynamic contact angle
abstract
The dynamics of a receding contact line of water drops on polymeric substrates (poly(methyl methacrylate), PMMA, and polycarbonate, PC) was studied using the sessile drop method. For smoother substrates, multiple stages were observed: the constant contact radius (CCR) mode, the constant contact angle (CCA) mode, and the mixed mode. In the CCA mode, the contact angle (CA) remained nearly constant and the receding dynamic CA could be identi?ed. The relation between the receding dynamic CA and the withdrawal rate was experimentally determined, and the receding dynamic CA was found to decrease with increasing liquid withdrawal rate. A decrease of 5–10° was found for PMMA substrates, whereas a decrease of 10–20° was observed for PC substrates for commonly applied liquid withdrawal rates. Our results quantitatively agree with those obtained by the capillary tube method and the plate method, and we demonstrated that the sessile drop method can serve as an alternative method for studying contact line dynamics. In addition, for the rough PC substrates, the CCA
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