褐煤半焦粉制备型焦的预案.doc

褐煤半焦粉制备型焦的研究 艾沙江1,2,王永刚1,林雄超1,张海永1,徐荣声1, 杨远平1,申恬1 (1，中国矿业大学（北京） 化学与环境工程学院，北京 100083； 2，潞安新疆煤化工集团新合实业有限责任公司，新疆哈密三道岭 839003） 摘要：为了合理利用褐煤热解过程中产生的半焦粉末，将其加工成高强度的型焦是一条有效途径。本研究以新疆三道岭褐煤热解半焦粉末为原料，采用复合粘结剂制备冶炼用型焦，考察粘结剂配比对型焦冷、热强度的影响规律。在优化粘结剂配比的基础上，考察了压力和炭化温度对型焦抗压强度的影响，并通过扫描电镜(SEM)解析了不同温度下型焦的微观结构。结果表明：型焦复合粘结剂的最佳配比为：淀粉3.65%、沥青2.81%、有机钙0.33%、三氧化二铁0.49%、水34%。在实验范围内，成型压力越大，型焦抗压强度越大。随着温度的升高，在300℃~500℃范围内型焦的抗压强度明显下降，在500℃~900℃范围内呈上升趋势。低温时，粘结作用主要以范德华力和静电力等物理作用方式为主，随着温度的升高，沥青和淀粉热解所产生的桥键成为粘结作用的主体，在温度超过500℃以后，焦粉自身以及其与有机钙、Fe2O3之间发生化学反应产生的粘性物质，促使型焦抗压强度提高。 关键词：型焦；粘结剂；炭化温度；抗压强度 Preparation of molding metallurgical coke formed by lignite char powder （School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing)，Beijing 100083，China） Abstract: The lignite char powder can be pressed to formed coke for its effective utilization. Lignite char powder from Xinjiang Hami Sandaoling was formed with composite binder to prepare molding metellurgical coke. The components ratio of blinder for formed coke was optimized by measuring the cold and thermal strength of the products. The effects of temperature and pressure on the compressive strength were investigated and the surface morphologies of the formed coke under different carbonization temperatures were studied by SEM. The results indicated that the optimum composition of the binder was 3.65% starch, 2.81% pitch, 0.33% organic calcium, 0.49% Fe2O3, 34% water. The compressive strength of formed coke increased with increasing pressure during briquetting. With the increase of temperature, the compressive strength of formed coke reduced significantly at 300~500°C, while then increased at 500~900°C The strength at low temperature mainly came from physical interactions such as Van der Waals forces and electrostatic force, with the increase of temperature, the bridge bonding formed by pyrolysis of starch and pitch was the main reason. As temperature was increased over 500°C, the compressive strength was enhanced