冶金粉尘硫容量的实验研究.pdfVIP

中国环境科学 2000,20(5) 457460 China Environmental Science 冶金粉尘硫容量的实验研究 叶树峰,杨学民,谢裕生,郭占成 中国科学院化工冶金研究所,北京 100080 摘要 在25~650 温度范围内测定了由Fe Ca Zn Mn 等氧化物组成的高炉冶金粉尘脱除H S 的硫容量.结果表明,反应温度 组成对 2 高炉冶金粉尘硫容量有较大影响.在 25~650 范围内,随着温度提高,硫容量增加 当温度低于350 时,Ca Zn Mn 氧化物对冶金粉尘的 脱硫起主要作用,且碳的存在有利于提高冶金粉尘对 H S 的吸附能力,可适度提高冶金粉尘硫容量 温度大于 350 时,Fe 氧化物对冶金粉 2 尘硫容量起主要作用,碳含量对冶金粉尘硫容量的影响较小,高炉冶金粉尘脱硫主要受Fe 氧化物脱硫反应及H S 在冶金粉尘中的扩散影响. 2 关健词 硫容量 脱硫 冶金粉尘 穿透时间 中图分类号 X703 1 文献标识码 A 文章编号2000 Study on the sulfur capacity of metallurgical dusts . YE Shu-feng, YANG Xue-min, XIE Yu-sheng, GUO Zhan-cheng (Institute of Chemical Metallurgy, Chinese Academy of Sciences, Beijing 100080, China).China Environmental Science. 2000,20(5) 457460 Abstract Sulfur capacity of metallurgical dusts was measured in temperature range from 25 to 650 . The experimental results show that sulfur capacity of metallurgical dusts may be considerably improved with temperature increase from 25 to 650 . Desulfurization ability of metallurgical dusts is mainly affected by contained oxides of zinc, calcium and manga- nese when temperature is less than 350 . Its desulfurization ability is decided by iron oxides when temperature is higher than 350 . Carbon content has a positive effect on metallurgical dusts desulfurization ability when temperature is less than 350 . This effect may be invalid when temperature is greater than 350 as desulfurization is decided by chemical reac- tion and H S diffusion in metallurgical dusts under this condition. 2 Key words sulfur capacity desulfurization metallurgical dusts penetration time 煤在我国能源结构中占 76%[1