Pb-Bi包晶合金定向凝固过程中带状组织的形成.pdfVIP

爱槊 Available online at www．sciencedirect，com ·乏；，ScienceDirect Trans．Nonferrous Met．Soc．China 22(2012)2131—2138 Transactions of NOllferrous Metals Society of China ■■■_■■■●__■■■■_____■■●■●●- www．tnmsc．cn Banding structure formation during directional solidification of Pb—Bi peritectic alloys HU Xiao—vcul，LI Shuang—ming：，AI Fan—ron91，YAN Hon91 1·School of Mechanical—Electrical Engineering，Nanchang University,Nanchang 33003 1，China； 2·State Key Laboratory ofSolidification Processing，Northwestern Polytechnical University,Xi’an 710072，China Received 7 September 20 1 1；accepted 1 April 20 1 2 Abstract：Directional solidification experiments on Pb—Bi peritectic alloys were carried out at very low growth rate fv=0．5 run／s) and high temperature gradient(G235刚1m)in an improved Bridgman furnace．The banding structures were observed in both hypoperitectie and hyperperitectic compositions(Pb-xBi，x=26％，28％，30％and 34％)．Tree—like primary n phase in the center ofthe sample surrounded by the peritectic b phase matrix was also observed．resulting from the melt convection．The banding microstructure，however,is fbund to be transient after the tree—like structure and only the peritectic phase forms after a few bands． Composition variations in the banding structure are measured to determine the nucleation undercooling for beth口and口phases．In a finite length sample，convection is shown to lead only to the transient formation of bands．In this transient banding regime．only a few bands with a vailable width are formed，and this transient banding process can occur over a wide range of compositions inside the two—phase peritectie region． Key words：directional solidification；segregation；Bridgman technique；Pb Bi alloys；banding structure 1 Introduction Several directional solidincation studies in peritectic systems have reported the formation of banding microstructure in which primary“phase and peritectic∥phase appear as bands[1—5]．TRIVEDI[6] has proposed a simple model of banding in peritectic systems