小论文的自我理解.pptxVIP

Hollow and Concave Nanoparticles via PreferentialOxidation of the Core in Colloidal Core/Shell Nanocrystals J. Am. arol Chem. SocHollow and concave nanocrystals find applications in many fields.Hollow and concave nanocrystals (NCs) are an interesting class of materials with potential applications in catalysis, energy storage, plasmonics and medicine.The authors ideasAuthor report a new route to these nanostructures that exploits the oxidation of Cu2-xSe/Cu2-xS core/shell nanocrystals with various etchants.Even though the Cu2-xSe core is encased in a thick Cu2-xS shell, the initial effect of oxidation is the creation of a void in the core.EXPERIMENTAL SECTIONSynthesis of CdSe (core) / CdS(shell) bullet in rod NCsCation exchange on Cd-based NCsEtching experiments performed on Cu-based NCsη=nCuCl2/nCu(a) a pristine sample;(b) a sample at initial stage of etching (η2) (c) a sample at moderate etching stage (η=4) and at (d) a late etching stage (η=9)η=4η=9η=9η=2η=2η=4η=4outlookFuture developments in this direction will include the study of this mechanism in other combinations of materials having a high diffusion cation in common.THANKN YOU