纤维素直接催化转化制乙二醇及其他化学品_从基础发现到潜在工业应用解说.pptxVIP

Direct catalysis of cellulose Direct catalytic conversion of cellulose to ethylene glycol cat Source of this paper： 1. Introduction 介绍 2. Catalyst development for CEG 纤维素直接转化为乙二醇的催化及的发展 2.1 tungsten carbide catalysts 碳化钨催化剂 2.1.1first application of tungsten carbide for CEG 碳化钨对CEG的首次应用 2.1.2high performance tungsten carbide catalyst 高绩效的碳化钨催化剂 2.2 M(8,9,10)-W bimetallic catalysts M（8,9,10）钨双金属催化剂 2.3 tungsten acid based composite catalysts 钨基复合催化剂 2.4 other metal based catalysts 其他金属基催化剂 3. reaction mechanism 反应机理 4. lignocellulosic feedstock conversion 木质纤维素原料转化 5. strategy to develop the CEG process for commercialization发展CEG工艺商业化策略 6. incorporating the CEG process into a bio-refinery process 将CEG的过程变成一个生物炼制过程 7. conclusions and prospects 结论与展望 Research background Ethylene glycol（EG) is the largest bulk polyol with a global consumption of up to 21 million ton/year . It is widely used in synthesis of polyester, antifreeze,ect .And is estimated to have increasing demand in the coming decades , currently , EG is mainly produced from petroleum ethylene by selectively catalytic oxidation and hydration Process . some recent endea- -vors have also been made for the catalytic preparation of EG from coal, which is also a fossil carbon resource . Using Cellulose to synthesize EG would notably contribute to alleviating the dependence on fossil energy resources and cut down on co2 emission . Meanwhile , this process could keep All the atoms from cellulose in the products , and thus it would have a very high atom economy , which is required for green chemistry. Research background The one-pot catalytic conversion of cellulose to ethylene glycol is a highly attractive way for biomass utilization to lessen the consumption of fossil energy resources. Reaction equations and conditions Reaction equations and conditions Reaction mechanism: For one thing : 1.The cellulose hydrolysis to form oligosac