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2005-Multiple Metal-Carbon Bonds for Catalytic Metathesis Reactions (Nobel Lecture).pdf

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2005-Multiple Metal-Carbon Bonds for Catalytic Metathesis Reactions (Nobel Lecture)

Metathesis Reactions DOI: 10.1002/anie.200600085 Multiple Metal–Carbon Bonds for Catalytic Metathesis Reactions (Nobel Lecture)** Richard R. Schrock* Its my great privilege to be here today, in a position I never thought possible. The story I will tell you I hope will give you some idea what I have contributed to the area for which the Nobel prize in chemistry was awarded this year. The story begins 32 years ago in 1973, the year the Nobel prize was shared by G. Wilkinson and E. O. Fischer. Wilkinsons Nobel lecture[1] concerned the nature of a single bond between a transition metal and a carbon atom in an alkyl group, and emphasized the fact that the metal–carbon bond is not inherently weak. E. O. Fischer in his Nobel Lecture[2] summarized the extensive chemistry of transition- metal “carbene” complexes[3,4] that contain a metal–carbon double bond discovered by him and his group in 1964 (Scheme 1).[5] He also reported new “carbyne” complexes that contain a metal–carbon triple bond.[6] It was clear that metal–carbon single bonds were of great importance in the emerging area of homogeneous catalysis. However, no catalytic reactions involving species that contain metal– carbon double or triple bonds were known. When I went to the Central Research Department of E. I. DuPont de Ne- mours and Company in 1972, transition-metal organometallic chemistry and homogeneous catalysis were of great interest as a consequence of their huge potential in organic chemistry and therefore in industry. In the early 1970s inorganic chemists knew that many transition metal species containing a metal–carbon bond are subject to various modes of decomposition that are much more rapid than in a non-transition-metal species such as Zn(CH2CH3)2 or Al(CH2CH3)3. The most common of these decomposition reactions involves transfer of a b hydrogen atom, from a metal-bound ethyl group (MCH2CH3) for example, to the metal center (M) to yield a metal hydride and an alkene. The relative stabilities of hi