本科毕业设计6-4.docxVIP

 本科毕业论文 题目W-C-Co, Ti体系的热力学计算 学生姓名李敏学 号1016020614教学院系材料科学与工程学院专业年级材料科学与工程2010级指导教师申文竹职 称实验师单 位西南石油大学 完成日期2014年6月12日 Southwest Petroleum University Graduation Thesis Thermodynamic Assessment of the W-C-Co, Ti Ternary System Grade: 2010 Name: Li Min Speciality: Materials Science and Engineering Instructor: Sheng Wenzhu School of Materials Science and Engineering 2014-6-12  摘要 硬质合金具有一系列优良性能，如高硬度、高强度、热稳定性等力学性能，因此在硬质材料领域占有重要地位。W-C-Co, Ti两个三元体系的热力学评估是利用CALPHAD（相图计算）方法来进行的。液相、溶体相和端际固溶体相的吉布斯自由能由亚正规深模型来进行了描述，金属间化合物是由亚点阵模型描述。从而通过计算优化得到W-C-Co三元系在500℃、800℃、1000℃、1200℃、1500℃、1800℃、2000℃和2500℃的等温截面，并计算出液相面以及垂直截面；也得到了W-C-Ti三元系在500℃、800℃、1000℃、1200℃、1500℃、1800℃、2000℃和2500℃的等温截面，以及垂直截面。 关键词：硬质合金；W-C-Co, Ti三元系；相图计算；热力学数据库；  Abstract Carbide has excellent mechanical properties of a range of properties such as high hardness, high strength, thermal stability, therefore it plays an important role in the field of hard materials. A thermodynamic assessment of the WC-Co, Ti ternary system was carried out by the CALPHAD (Calculation of Phase Diagrams) method. The Gibbs free energies of the liquid and solution phases were described by the subregular solution models, and those of intermetallic compounds were described by the sublattice model. The isothermal sections in 500 ℃, 800 ℃, 1000 ℃, 1200 ℃, 1500 ℃, 1800 ℃, 2000 ℃ and 2500 ℃, the liquid surface and a vertical section of WC-Co ternary system were carried out ; The isothermal sections in 500 ℃, 800 ℃, 1000 ℃, 1300 ℃, 1500 ℃, 1800 ℃, 2000 ℃ and 2500 ℃ and a vertical section of WC-Ti ternary system were carried out Keywords: Carbide; W-C-Co, Ti ternary system; CALPHAD; Thermodynamic database西南石油大学本科毕业论文 WC-Co, Ti体系的热力学计算  PAGE \* MERGEFORMAT 35 目录 TOC \o 1-3 \h \z \u   HYPERLINK \l _Toc389676776 1 绪论  PAGEREF _Toc389676776 \h 1  HYPERLINK \l _Toc389676777 1.1硬质合金特点、应用、和国内外发展现状  PAGEREF _Toc389676777 \h 1  HYPERLINK \l _Toc389676778 1.1.1硬质合金特点、应用  PAGERE