97年——砷酸受孔隙水的运输速度的影响.pdf

Environ. Sci. Technol. 1997, 31, 704-709 Effects of Pore Water Velocity on particle and film diffusion may play a significant role in the kinetics of AsO4 sorption onto soil mineral phases (5). The the Transport of Arsenate extent to which these kinetic processes may affect the transport of AsO4 through soils and/or aquifer materials is unclear. JEFFREY E. DARLAND Sorption processes influenced by slow mass transfer rates Department of Environmental Science and Engineering, may be subject to chemical (sorption related) nonequilibrium Oregon Graduate Institute of Science and Technology, under transport conditions (11). Under these situations, it Portland, Oregon 97291-1000 is characteristic to observe changes in the shape (e.g., tailing) of solute breakthrough curves as a function of pore water WILLIAM P. INSKEEP* velocity (11-14). Moreover, transport-derived rate constants Department of Plant, Soil, and Environmental Sciences, representing the sorption process may vary with pore water Montana State University, Bozeman, Montana 59717 velocity (11, 14, 15), indicating that the diffusional processes controlling sorption rates are sensitive to the mixing envi- ronment (16). While there has been substantial research on batch The potential for AsO4 to exhibit sorption-related nonequilibrium equilibrium sorption rea