材料科学与工程基础作业讲评4.pptVIP

第七次作业中文;3-22 CaTiO3为标准钙钛矿型结构，简述其结构特征，分析其中钙离子、钛离子和氧离子的配位数。 ;3-24 简要说明硅酸盐的几种结构单元 的主要特点。 岛状结构：SiO四面体不共顶，非桥氧比例大，需形成较多离子键，(4) 环状结构：SiO四面体共二顶成环，非桥氧比例较大， (2) 链状结构：SiO四面体共二顶成链，非桥氧比例较大，(2) 层状结构：SiO四面体共三顶成层，非桥氧比例较小，需形成较少离子键，(1) 架状结构：SiO四面体共四顶（架状），无非桥氧，不需再成离子键，(0);2-22由X射线衍射数据显示，MgO立方体的单位晶胞尺寸是0.412nm，其密度3.83Mg/m3，请问在每单位晶胞中有多少Mg2+离子和O2-离子? MgO: 40.31 3.83g/cm3 = [40.31×x] / [6.02×1023个/mol ×(0.412×10-7cm)3] x = 4 (4个Mg2+, 4个O2-);; 英文 3.29 On the basis of ionic charge and ionic radii, predict the crystal structures for the following materials: (a) CsI, (b) NiO, (c) KI, and (d) NiS. Justify your selections. ;3.38 Cadmium sulfide (CdS) has a cubic unit cell, and from x-ray diffraction data it is known that the cell edge length is 0.582 nm. If the measured density is 4.82 g/cm 3 , how many Cd 2+ and S 2— ions are there per unit cell? 每个晶胞中Cd和S数目相等x个. x?M/NA= ρ ? a3, x=4, So, there are 4 Cd 2+ and S 2- ions in per unit cell. ;3.41 A hypothetical AX type of ceramic material is known to have a density of 2.65 g/cm 3 and a unit cell of cubic symmetry with a cell edge length of 0.43 nm. The atomic weights of the A and X elements are 86.6 and 40.3 g/mol, respectively. On the basis of this information, which of the following crystal structures is (are) possible for this material: rock salt, cesium chloride, or zinc blende? Justify your choice(s).;3.63 For each of the following crystal structures, represent the indicated plane in the manner of Figures 3.24 and 3.25, showing both anions and cations: (a) (100) plane for the rock salt crystal structure, (b) (110) plane for the cesium chloride crystal structure, (c) (111) plane for the zinc blende crystal structure, and (d) (110) plane for the perovskite crystal structure.;3.42 The unit cell for Mg Fe2O4 (MgO-Fe2O3) has cubic symmetry with a unit cell edge length of 0.836 nm. If the density of this material is 4.52 g/cm3 , compute its atomic packing factor. For this computation, you will need to use i