Silica Shell Gold Core Nanoparticles- Correlating Shell Thickness with the Plasmonic Red Shift upon Aggregation英文.pdfVIP
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RESEARCH ARTICLE
Silica Shell/Gold Core Nanoparticles: Correlating Shell Thickness with
the Plasmonic Red Shift upon Aggregation
Alan Vanderkooy, Yang Chen, Ferdinand Gonzaga, and Michael A. Brook*
Department of Chemistry and Chemical Biology, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1
bS Supporting Information
ABSTRACT: Di?erences in the wavelengths of the surface
plasmon band of gold nanoparticles (AuNP) à before and after
particle aggregation à are widely used in bioanalytical assays.
However, the gold surfaces in such bioassays can su?er from
exchange and desorption of noncovalently bound ligands and
from nonspeci?c adsorption of biomolecules. Silica shells on the
surfaces of the gold can extend the available surface chemistries for bioconjugation and potentially avoid these issues. Therefore,
silica was grown on gold surfaces using either hydrolysis/condensation of tetraethyl orthosilicate 1 under basic conditions or
diglyceroxysilane 2 at neutral pH. The former precursor permitted slow, controlled growth of shells from about 1.7 to 4.3 nm
thickness. By contrast, 3à4 nm thick silica shells formed within an hour using diglyceroxysilane; thinner or thicker shells were not
readily available. Within the range of shell thicknesses synthesized, the presence of a silica shell on the gold nanoparticle did not
signi?cantly a?ect the absorbance maximum (~ 5 nm) of unaggregated particles. However, the change in absorbance wavelength
upon aggregation of the particles was highly dependent on the thickness of the shell. With silica shells coating the AuNP, there was a
signi?cant decrease in the absorbance maximum of the aggregated particles, from ~578 to ~536 nm, as the shell thicknesses
increased from ~1.7 to ~4.3 nm, because of increased distance between adjacent gold cores. These studies provide guidance
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