Inorganic hybrid silica matrix organic polymer C16 monolithic capillary column preparation and performance of.docVIP

 PAGE \* MERGEFORMAT 19 Inorganic hybrid silica matrix organic polymer C16 monolithic capillary column preparation and performance of Of: Wu Qiong Wang Jin Yingzhi Liu Jinhua North Park [Abstract] The dual functional groups of 3 (trimethoxysilyl) propyl methacrylate siloxane hydrolyzed in acidic aqueous solution polymerization, and then lead to conditions in the hot sixteen ester with methyl methacrylate double bond polymerization, preparation of a new class of inorganic silica hybrid organic polymer monolithic column electrochromatography matrix to achieve the overall silica column and the organic polymer matrix method of monolithic column system into one column. proposed mercury control smoking sol mixture into the capillary where appropriate, to obtain a flat overall column stationary phase interface simple method of operation. optimizes the overall column preparation conditions, using scanning electron microscopy and nitrogen adsorption surface area analyzer column on the overall structure of the material were characterized by the average material surface area of #8203;#8203;103.4 m2 / g, in diameter and mainly distributed in the range of 3 ~ 7 nm. explores the operating voltage, buffer concentration, pH value and organic modifier content on the impact of electroosmotic flow velocity. preparative column using the baseline 7 isolated neutral aromatic substances. column efficiency of naphthalene plate number of 54000 / m; continuous operation of 5 times the retention time of RSD is 0.9%, capacity factor of 0.6% RSD; continuous operation of 3 d, retention time RSD was 1.2%, capacity factor of 0.8% RSD; different batches of three monolithic column, the retention time RSD was 8.7%, capacity factor of 5.7% RSD. [Keywords:] the whole column; capillary electrochromatography; inorganic silica hybrid organic polymer matrix; Preparation Abstract A novel type of inorganic silica gel organic polymer mixture based capillary monolithic column was prepared sing