化石燃料成因新解.doc

化石燃料成因新解 马双忱，别璇，孙智滨，陈公达， 焦坤灵 （华北电力大学（保定） 环境学院，河北 保定 071003） E-mail：msc1225@163.com 摘 要：限碳背景下，随着煤、石油、天然气这些化石燃料的消耗日益增加，研究碳的自然循环及化石燃料的真正成因具有重要的现实意义。本文以煤炭为例，从国内外关于煤炭起源的一般性研究出发，指出煤炭源自植物的储量、赋存、分布等矛盾之处，在石油和煤炭来源“无机说”的基础上，通过热力学趋向论证和动力学速率分析、地壳中碳酸盐和水的含量分析、煤中常量组分和惰性组分分析，提出煤炭等化石燃料源自地下碳酸盐等含碳物种的化学转化这一全新观点，从而打通了石灰石、白云石等地下含碳物种向煤、石油、天然气化学转化的渠道。基于此认识，构建了新的自然界碳循环过程图示，该碳循环图更加完美的诠释了碳的释放与自然循环。 关键词： 煤炭；来源；碳酸盐；碳循环 New analysis about the origin and formation of fossil fuel MA Shuang-chen, Bie Xuan , SUN Zhi-bin, CHEN Gong-da，Jiao Kunling (School of the Environment, HYPERLINK app:ds:NorthNorth HYPERLINK app:ds:ChinaChina HYPERLINK app:ds:ElectricElectric HYPERLINK app:ds:PowerPower HYPERLINK app:ds:UniversityUniversity (Baoding),Baoding 071003,Hebei,China) Abstract: With the increasing consumption of fossil energy such as coal, oil and natural gas in limited carbon world, it will have great realistic meanings to study natural carbon cycle and real source of fossil energy. This article takes coal as an example, pointing out the contradictions that coal comes from the forest through the general research conclusion. There are lots of contradiction in the theory that coal comes from the forest, such as the reserves, occurrence state and distribution of the coal. We put forward a new point of view that coal comes from carbonate and other carbonaceous species by dynamic demonstration, thermodynamic analysis, analyzing the content of carbonate and water in the earth’s crust, the analysis about the major components and inert components of coal. So there will be a new channel between the chemical conversion about limestone、dolomite and other carbonaceous species. Basing on this understanding, we propose a more perfect interpretation about the natural carbon cycle. Keywords: coal; source; carbonate; carbon cycle在当今世界上，被人们广泛接受的一种观点是煤炭和石油是古代植物和动物埋藏在地下经历了复杂的生物化学和物理化学变化逐渐形成的固体和液体可燃性矿物，即煤炭和石油来源于植物和动物[1-7]。 近些年来，关于石油、天然气来源的“无机说”逐渐被人们熟知，但是关于煤炭的来源并没有出现更新的说法。不过在很多方面上的矛盾都表明，煤来源于树木的理论有很大的局限性[8-1