催化裂化汽油脱硫添加剂的研究进展_李春义.pdf

2005 年　第29 卷　　　　　　　　　石油大学学报(自然科学版)　　　　　　　　　　Vol.29 　No.3 　第3 　　　　　　　　Journ l of the University of Petroleum, Chin 　　　　　　　　Jun.2005 　　:1000-5870 (2005)03-0148-09 催化裂化汽油脱硫添加剂的研究进展 1 1 2 1 1 李春义, 杨红燕, 顾艳萍, 山红红, 杨朝合 (1.中国石油大学重质油国家重点实验室, 山东东营 25706 1;2.大连石油化工公司, 辽宁大连 116610) :, , , 。 ZnO/Al O , TiO /Al O , Mg(Al)O 。ZnO/Al O TiO /Al O 2 3 2 2 3 2 3 2 2 3 30%, 63%, 250 μg/g 。 32.63%, 4 10.56 μg/g。 :;;;; :TE 624.41　　　:A Research advances on desulfuration additives for fluid catalytic cracking gasoline 1 1 2 1 1 LI Chun-y i , YANG Hong-y n , GU Y n-ping , SHAN Hong-hong , YANG Ch o-he (1.S tateKey Laboratory of Heavy Oil Processing in China University of Petroleum, Dongying 257061, China; 2.Dalian Petroleum Corporation of Chemical Industry, Dalian 1166 10, China) Abstract:In fluid c t lytic cr cking (FCC)g soline, most of sulfur is in the form of thiophene or lkyl-thiophenes.Thio- phene with the conjug ted structure simil r to benzene, is more difficult to be desulfurized by c t lytic cr cking.The cr ck- ing desulfur tion mech nism of thiophene compound w s discussed in FCC condition.And different desulfur tion dditives for FCC g soline reported in liter tures, such s ZnO/Al O , T iO /Al O , Mg(Al)O spinel, nd vitriol-cont ining dditives 2 3 2 2 3 were summ rized.These dditives were reported to h ve good sulfur remov l effect, how ever, the bsolute desulfur tion content is under 250 μg/g.The bsolute sulfur remov l content of the new desulfur tion dditives c n re ch 410.56 μg/g. Key words:c t lytic cr cking;g soline;desulfur tion;dditive;rese rch dv nce 　　, , (FCC )。 [ 1, 7-16] 。 [1]