硝酸盐催化碳酸二甲酯与苯酚合成苯甲醚.pdfVIP

2009 38 8 PETROCHEM ICAL T ECHNOLOGY # 897# 1, 2 1 1 1 陈 冰 , 赵 宁, 魏 伟 , 孙予罕 ( 1. , 030001; 2. , 100049) [] (DM C), , , 200 e n (DM C) Bn () = 2. 0C sNO 1. 0% 10 h , 3 98. 1% , 99. 2% , 600 kJ/m o l, , , , ; 600 kJ/m o l, , , ; [] ; ; ; [] 1000 - 8144( 2009) 08- 0897 - 06 [ ] TQ 032. 4 [] A Synthesis of Anisole from Phenolw ith Dim ethyl Carbonate over Inorganic N itrate 1, 2 1 1 1 Chen Bing , Zhao N ing , W eiW ei , Sun Yuhan ( 1. State Key Labo rato ry o f C oalC onversion, Institute o f C oalChem istry, Chinese A adem y o f S ien es, Taiyuan Shanx i030001, Ch ina; 2. G raduate U n iversity of Ch inese A adem y of S ien es, B eijing 100049, Ch ina) [Abstract] Syn thesis of anisole by O-m ethy lation of pheno l w ith dmi ethy l arbonate( DM C ) over n itrate ataly sts w as studied. U nder optmi al rea tion ond itions: C sNO3 as ataly s,t rea tion tem perature 200 e , n ( DM C ) Bn ( phenol) 2. 0 and ataly st amount 1. 0% ( based on m ass of raw m aterials) and rea tion tmi e 10 h, pheno l onversion and anisole sele tivity w ere 98. 1% and 99. 2%, respe tively. A tiv ity of n itrate ataly st relates to ion ization energy of its metalli ation. W hen the ion ization energy w as less than 600 kJ/mo ,l the n itrate w ould be m ore a tive in the methylation, but above 600 kJ/mo l the situation w as not as prom ising. Phenol onversion depended alm ost linearly on ion ization energy. The less the ion izati