固体氧化物燃料翟阽池.pdfVIP

ISSN Physics of the Solid State, 2010, Vol. 52, No. 8, pp. 1688–1693. © Pleiades Publishing, Ltd., 2010. Original Russian Text © K.R. Zhdanov, M.Yu. Kameneva, L.P. Kozeeva, A.N. Lavrov, 2010, published in Fizika Tverdogo Tela, 2010, Vol. 52, No. 8, pp. 1570–1575. MAGNETISM AND FERROELECTRICITY Spin Transition and Thermal Expansion in the Layered Cobaltite GdBaCo2O5.5 a, b a, a a, b K. R. Zhdanov , M. Yu. Kameneva *, L. P. Kozeeva , and A. N. Lavrov a Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090 Russia * email: kam@niic.nsc.ru b Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090 Russia Received November 25, 2009 Abstract—The electrical conductivity and thermal expansion coefficient of GdBaCo O samples have been 2 5.5 measured in order to reveal the mechanism of the metal–insulator transition in cationordered cobaltites RBaCo O (where R is a rareearth element) and its relation to the change in the spin state of cobalt ions. It 2 5.5 has been established that the unit cell volume considerably increases upon the transition to the metallic state at T ≈ 360–365 K and that the thermal expansion exhibits anomal