泡沫镍光催化材料及其催化活性.pdfVIP

学兔兔 化 工 进 展 ·1972· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2011年第3O卷第9期 复合电沉积制备TiO2／泡沫镍光催化材料及其催化活性 于化江 ，熊 亮 ，熊中琼 ，张国庆 ( 河北沧州师范学院化学系，河北 沧州 061001； 广东工业大学材料与能源学院，广东 广州 510006) 摘 要：采用复合电沉积方法制备了TiO2／泡沫镍光催化材料，通过扫描电子显微镜(SEM)和能量色散谱(EDS) 分别对纳米复合镀层进行了形貌和成分表征，同时研究了在镀液中添加不同表面活性剂对光催化材料镀层的影 响。讨论了TiO2／泡沫镍光催化材料对大肠杆菌和小球藻的光催化活性。结果表明：在本实验的电沉积工艺条件 下，泡沫镍基底上获得了微粒分布均匀、Ti的质量分数为5．97％的纳米TiO2一Ni复合沉积层。添加了阴离子表面 活性剂的光催化材料表面TiO2颗粒具有良好的分散性。TiO2／泡沫镍光催化材料处理含大肠杆菌水样，反应30min 灭活率达到60．1％，反应2 h灭活率达到99．9％；处理水中的小球藻溶液，初始3 h内，小球藻溶液中所含叶绿 素a从初始的98．2 mWm 降至38．2 mg／m 。 关键词：TiO2／泡沫镍；复合电沉积；光催化；染料；大肠杆菌；灭活 中图分类号：X 703 文献标志码：A 文章编号：1000—6613(2011)09—1972—05 Preparation of foam nickel-supported nanosized TiO2 by composite electr0dep0sitiOn and its ph0t0catalytic performance YUHuajiang ，XIONGLiang ，XIONGZhongqiong ，ZHANG Guoqing ( Department of Chemistry，Cangzhou Teachers’College，Cangzhou 061001，Hebei，China； FacuRy ofMaterial and Energy，Guangdong University ofTechnology，Guangzhou 510006，Guangdong，China) Abstract：Foam Ni／TiO2 nano composite coatings were prepared by composite electrodepositon from Watts bath containing nanosized WiO2 particles．The surface morphologies of the composite coatings were characterized by scanning electronic microscopy(SEM)．The composition of the coatings was analyzed by energy dispersive spectroscopy(EDS)．The effect of adding surfactant in the plating solution on the composite coatings was alSO studied．The photocatalytic activity of the foam Ni／TiO2 nano composite coatings on colibacillus and chlorella was discussed．The results showed that t