制备条件对Pt／SO42-／ZrO2．AI2O3异构化性能的影响.pdfVIP

学兔兔 化 工 进 展 2015年第34卷第2期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·419· 制备条件对Pt／SO42-／ZrO2．AI2O3异构化性能的影响 乐晓光，徐俊，宋月芹，周晓龙 (华东理工大学化工学院石油加工研究所，上海200237) 摘要：采用沉淀法制备了Pt／SO42-／ZrO2．A12O3(PtSZA)催化剂，考察了氢氧化锆水凝胶干燥速率、锆盐浓度、铂 含量、A12O3和 SO42-添加顺序等制备条件对PtSZA异构化性能，尤其是低温异构化性能的影响，并用XRD和 TG对催化剂进行了表征。结果表明，提高水凝胶的干燥速率降低了PtSZA催化剂中的硫含量，大大提高了催化 剂中的单斜相，进而导致了催化剂低温失活加速以及高温活性下降。较低或较高的锆盐浓度劣化了PtSZA的低 温异构化稳定性，以0．4～0．6mol／L硝酸氧锆制备的催化剂硫含量和四方相氧化锆含量较高，异构化活性相对较 好，A1，O 和S042-添加顺序对PtSZA异构化性能没有明显影响。 关键词：制备；干燥；Pt／S042-／ZrO2．A12O3；烷烃；加氢异构 中图分类号：TQ 032．4 文献标志码：A 文章编号：1000—6613(2015)02—0419—06 DoI：10．16o85~．issn．1000—6613．2015．02．019 Effect of preparation conditions on isomerization performance of Pt]SO42-／ZrO2．Al2O3 catalyst LEXiaoguang，XUJun，SONG Yueqin，ZHOUXiaolong (Petroleum Processing Research Center，School of Chemical Engineering，East China Universit)r of Science and Technology，Shanghai 200237，China) Abstract：Pt／SO4 ／ZrO2一A1203 fPtSZA)catalyst was prepared by the precipitation method．The influences of preparation conditions，such as drying rate of Zr(OH)4 hydrogel，zirconium concentration，platinum content and addition order of AI203／SO4 一on isomerization performance of PtSZA catalyst，especially low reaction temperature isomerization perform ance were investigated．The crystalline structure and sulfur content of PtSZA were characterized with XRD and TG，respectively． Increase of drying rate of Zr(OH)4 hydrogel led to decrease of sulfur content and remarkable increase o