将水热固化无机废料转变为建筑材料的研究.pdfVIP

维普资讯 No．5 陕西科技大学学报 0ct．2004 · 8 · JOURNALOFSHAANXIU~qlVERSITYOFSCIENCE TECHNOLOGY Vol_22 。 文 章编号 ：1000—58ll(2004)05—0008—09 HYDRoTHERM AL SoLIDIFICATIoN oF INoRGANIC W ASTERSTo BUILDING MATERIALS JING Zhen—zi。NorihisaMatsuoka ，JIN Fang—ming ，ToshiyukiHashida ，NakamichiYamasaki (1．GraduateSchoolofEnvironmentalStudies，TohokuUniversity，Aoba20，Aoba—kuSendal980—8579，Japan；2．Fracture andReliabilityResearchInstitute。TohokuUniversity，Aoba20，Aoba—kuSendal980—8579，Japan) Abstract：Municipalincinerationash (MIA)hasbeensolidifiedbyhydrothermalprocessing．TheMIA wasfirstcompacted inamodeIat5~ 20MPaIandthenhydrothermallycuredinanautoclaveattempera— ture150~ 250C for10～ 72h．ExperimentaIresultsshowedthatthetensilestrength ofsolidifiedbody wasverysensitivelytoconcentrationofNaOH solutionandthecementcontentintheM IA．Theauto— clavecuringtemperatureexertedasignificantinfluenceonmechanicalpropertyofspecimens．However， ahighercuringtemperatureleadedtodecreaseintensilestrength．Itwasshownthatthestrengthdevel— opmentwasduemainlytotheformationoftobermorhe．Amountsofdissolvedheavym etalsfrom theso— lidifiedbodiesweredetermined，andourresultsdemonstratedthattheheavymetalswasvery low well below theregulatoryleveloftheenvironmentalquality standardinJapan．Assuch，thehydrothermal processingmayhaveahighpotentialforrecycIing／reusingMIA onalargescale． Keywords：miunicipalincinerationash：solidification：hydrothermalprocessing；heavymetals；becycling CLC Number：0782 ．2：TU5 DocumentCode：A 0 Introduction Becausemorethan6milliontonsofincinerationashfrom municipalgarbageisgeneratedannuallyin Japan，thereisanurgentrequirementtodevelopanenvironmentallyacceptablerecycling／reusingtech— nology．Itiswellknownthatthemunicipalincinerationash(MIA)hasbeenusedascement(Kikuchi， 2001)andceramicmaterials(Cheeseman，2003)，andusedt