悬浮聚合酚醛树脂基制动材料的摩擦学性能.pdfVIP

学兔兔 第16卷第6期 粉末冶金材料科学与工程 2011年12月 Vbl_16No 6 Materials Science and Engineering of Powder Metallurgy Dec．201l 悬浮聚合酚醛树脂基制动材料的摩擦学性能 林有希，余大刚，高诚辉，何福善 (福州大学 机械工程及自动化学院，福州 350002) 摘 要：采用悬浮聚合法制备热固性酚醛树脂，通过红外光谱分析和热重分析对该悬浮聚合酚醛树)]~(suspension． polymerization phenolic resin，缩写为SPPR)的结构和热学性能进行分析。用模压成形工艺制备树脂基制动复合材 料，利用JF150D．II型摩擦磨损试验机测试该材料与HT250灰铸铁在100～350℃盘面温度范围内的滑动摩擦性能。 结果表明，SPPR的热分解温度为396℃，在400℃时质量损失率为12．7％，具有较好的热稳定性。经过正交试 验得到树脂基制动复合材料的优化配方，制备的复合材料和HT250灰铸铁对摩，在100～350℃升温过程中，摩擦 因数平均值为0．41，波动值为0．07，350℃的摩擦因数和最大摩擦因数的比值 350 )为1。和国内外优质产品 相比，该复合材料的摩擦因数适中，磨损率较低，摩擦稳定性和抗热衰退性能优异。 关键词：酚醛树脂；悬浮聚合；制动材料；摩擦稳定性 中图分类号：THll7．1 文献标识码：A 文章编号：1673—0224(2011)6-815-05 Friction and wear properties of suspension-polymerization phenolic resin based composites LIN You·xi，YU Da—gang，GAO Cheng—hui，HE Fu—shan fCollege ofMechanical EngineeringAutomation，Fuzhou University,Fuzhou 350002，China) Abstract：Thermosetting phenolic resins were synthesized by suspension polymerization(SPPR)．The structure and thermal properties of the resin were analyzed by infra—redspectrum，thermo mass(gravimetric)analysis．The brake composites based on SPPR for automobile were prepared by compression molding．The effect of operating temperature on the dry sliding friction and wear properties of brake composites was investigated．The sliding experiments were carried out on a model JF150D—II pin—on—disc tribometer at selected temperatures in the range of 100~C-350℃．The results show that thermal decomposition temperature of the therm osetting phenolic resins is 396~C and losing mass is 1 2