缓释型聚羧酸系高效减水剂的研发与应用.pdfVIP

学兔兔 2010年 第 6期 (总 第 248期 ) 混 凝 土 原材料及辅助物料 Number 6 in 2O1O(Total No．248) Concrete MATEluAL AND ADMINICLE doi：10．3969~．issn．1002—3550．2010．06．021 缓释型聚羧酸系高效减水剂的研发与应用 盛喜忧，王万金，贺 奎，郑丽丽 (北京市建筑工程研究院，北京 100039) 摘 要：研究开发了一种缓释型聚羧酸系高效减水剂，具有高保坍性，能够有效的控制新拌混凝土坍落度损失速度。通过分子结构的设 计，选择相应醚类大单体、小单体合成具有缓释功能的减水剂。探索了分子侧链、分子主链及反应时间和温度对产品性能的影响。小单体和 聚醚大单体的相对摩尔比 5、减水剂分子量15 000-25 000、反应时间3~6 h、反应温度60-90℃时合成减水剂的缓释保坍效果最佳。 关键词：聚羧酸；高效减水剂；缓释；混凝土坍落度 中图分类号：TU528．042．2 文献标志码：A 文章编号： 1002—3550(2010)06—0068-03 Development and application of sustained-release type polycarboxylic high efficiency water reducing agent SHENGXi-you，WANG wanqin，HEKui，ZHENGLi一／／ (BeijingBuildingConstructionResearchInstitute，Beijing 100039，China) Abstract： This study developed a sustained—release type polycarboxylic high efficiency water reducing agent．with high slump nature。can effec- tively control the mte of loss of fresh concrete slump．Through the designing of molecular structure，we selected the appropriate large polyether monomer and small monomers and synthesized a type of water reducing agent with slow-release function．The impact of molecular side chains， main chain，the reaction time and temperature on product properties was explored．Th e water-reducing agent have the best slow—release slump whenthemolarratioofsmallandpolyethermonomeris atthe rangeof4to 5，molecularweight of15 000-25 000，reactiontimeis atthe rangeof 3--6 h．the reaction temperature is at the range of60-90℃． Key words： polyearboxylic acid；high efficiency water reducing agent；sustained·release；concrete slump 性功能大单体，并选择带有相应聚羧酸基团的不饱和小单体， 0 引言