新型聚羧酸接枝保坍剂的合成与性能研究.pdfVIP

学兔兔 全国中文核心期刊 钎 建巍粉 中国科技核心期刊 新型聚羧酸接枝保坍剂的合成与 性能研究 刘春燕 ，王自为 ，卫晓慧 ，任建国 ，裴继凯 (1．山西大学 化学化工学院，山西 太原 030006； 2．山西合盛邦砼建材有限公司，山西 太原 030006) 摘要：介绍一种新型聚羧酸接枝保坍剂(JL—PC)的合成，研究了该保坍剂在混凝土中的使用效果。结果表明，与单掺减水剂 (HS—1)的混凝土相比，复掺减水剂(HS一1)和保坍剂(JL—PC)的混凝土在保坍性能上具有明显的优势。尤其当保坍剂JL—Pc掺量为 水泥用量的O．09％时，混凝土的各项性能达到最佳：减水率达31．9％，泌水率降至0．4％，坍落度达到25．9 cm，60min内坍落度基本无 损失；3、7、28 d抗压强度及抗压强度比也达到最大。 关键词：接枝共聚；混凝土保坍剂；混凝土减水剂；复掺；性能 中图分类号：TU528．042 文献标识码：A 文章编号：1001—702X(2012)02-0042—04 Research on synthesis and performance of a novel polycarboxylate grafted slump retaining agent LIU Chunyan ，WANG Ziwei’， Xiaohui ，REN Jianguo ，册 ，Jikai (1．School of Chemistry and Chemical Engineering，Shanxi University，Taiyuan 030006，Shanxi，China~ 2．Shanxi HeSheng BangTong Building Materials Co．Ltd．，Taiyuan 030006，Shanxi，China) Abstract：The synthesis of a novel poly—carboxylie grafted slump retaining agent named as JL—PC has been introduced and the use effect of the slump retaining agent in concrete experiments has been particularly studied．The results indicate that the concrete mixed with water reducer(HS一1)and slump retaining agent(JL-PC)has a better performance of slump retention than the concrete only mixed with water reducer(HS-1)．In particular，when the content of slump retaining agent is 0．09％ of cement amount，the properties of concrete reach high—points：water-reducing rate is 31．9％．The slump loss is 25．9 am，which basically keep no change within 60 min．The bleeding rate drops to O．4％．The compressive strength and the rate of co