聚羧酸系减水剂引入聚氧乙烯侧链的新方法.pdfVIP

学兔兔 杆 魄粉 全国中文核心期刊 聚菝酸系减水剂引入聚氧乙烯侧链的 新方法 杜鹏飞，孙永强，康保安，田春花，刘广宇，史修启，张勇 (中国日用化学工业研究院，山西 太原 030001) 摘要：如何接枝聚氧乙烯长侧链己经成为聚羧酸系减水剂合成的核心问题。采用酯基乙氧基化的方法向聚丙烯酸甲酯中引入 一 定数目的环氧乙烷(EO)，得到甲氧基封端的聚氧乙烯侧链。从而为聚羧酸系减水剂引入聚氧乙烯侧链提供了一种新方法。在自制 的酯基乙氧基化催化剂MCT一09催化下，对不同分子量的聚丙烯酸甲酯进行了乙氧基化反应。采用红外光谱对产物结构进行了表 征，通过测试皂化值来确定其链均EO加合数。 关键词：聚羧酸系减水剂；聚氧乙烯侧链；酯基乙氧基化；MCT一09 中图分类号：TU528．042．2 文献标识码：A 文章编号：1001—702X(2010)04—0059—03 A new method of introducing polyoxyethylene into the polycarboxylic acid water-reducer DU Pen~Cei，SUN Yongqiang，KANG Baoan，TIAN Chunhua，LIU Guangyu，SHI Xiuqi，ZHANG Yong (China Research Institute of Daily Chemical Industry，Taiyuan 030001，Shanxi，China) Abstract：How to graft the polyoxyethylene onto the main chain has become the key problem for synthesis of the polycarboxylic acid type water-reducer．Certain amount of ethylene oxide(EO)was introduced into poly methyl acrylate(PMA)by the method of ester ethoxylation and polyoxyethylene side chain terminated with methoxy Was obtained．Consequently，this provided a new method of introducing polyoxyethylene long side chain into the polycarboxylic acid type water—reducer．With the help of self-made ester ethoxylation catalyst MCT-09，PMA of different molecular weights were carried out the ethoxylation．Finally，the structure of PMA ethoxylate was characterized by IR．The average EO number of the ethoxylate was obtained by determ ining its saponification value． Key words：polycarboxylic acid type water-reducer；polyoxyethylene side chain；ester ethoxylation；MCT-09 聚羧酸系减水剂通过调节聚氧乙烯长侧链的分子量来增 而进行乙氧基化反应，从而直接生成甲氧基封端的聚氧乙烯 加立体位阻作用而