酮醛树脂改性呋喃树脂工艺.pdfVIP

学兔兔 Apr．2009 VoI．58 NO．4 酮醛树脂改性呋喃树脂工艺 黄仁和 ，王 旭。，陈丽慧 (1．山东科技大学青岛校区，山东青岛266510；2．国家开发银行宁夏分行，宁夏银川750000) 摘要：在现有呋喃树脂合成工艺的基础上，考察酮醛改性自硬呋喃树脂工艺条件：丙酮与额外添加甲醛量、糠醇含 量、糠醇添加方式对改性呋喃树脂砂强度的影响，从而得出酮醛改性呋喃树脂合成的最佳工艺条件，并且利用红外光 谱对丙酮与甲醛反应产物以及它们与糠醇反应产物的结构进行分析，从而得出酮醛改性呋喃树脂反应机理。 关键词：呋喃树脂；工艺条件；红外光谱；反应机理；酮醛树脂改性 中图分类号：TG221 文献标识码：A 文章编号：1001—4977(2009)04—0380—03 Technology of Modified Furan Resin by Ketone— Formaldehyde Resin HUANG Ren．he’，WANG Xu2。CHEN Li．hui’ (1．Shandong University of Technology and Science，Qingdao．26651 0，Shandong，China； 2．China Development Bank Ningxia Branch，Yinchuan 750000，Ningxia。China) Abstract：Synthetic technology condition of modified furan resin by ketone-formaldehyde resin was studied on the base of existing synthetic technology，including effect of the proportion of acetone and accessional formaldehyde．the content and adding method of furfuraI alcohoI on strength of modified furan resin．Consequently the optimaI synthetic technology of modified furan resin was obtained．the reaction products of ketone and formaldehyde as welI as ketone and furfural were analyzed by infrared spectroscopy(1R)，and sequentially the reaction mechanism of modified furan resin by ketone—formaldehyde resin was obtained． Key words： furan resin；technology condition；infrared spectroscopy；reaction mechanism； modification with ketone—formaldehyde resin 随着中国铸造业的飞速发展，各种树脂砂竞相推 性能，具有一定现实意义。利用酮醛改性脲醛呋喃树 出和推广应用。用呋喃树脂砂生产的铸件，具有尺寸 脂就是一种较好方法，酮醛改性呋喃树脂具有粘度低、 精度高、表面光洁度好、废品率低，而