Co-Mo#-AI203催化剂上煤焦油加氢裂化工艺-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2014年第43卷第5期 PETROCHEMICAL TECHN0LOGY ·5l7· Co—Mo#一AI203催化剂上煤焦油加氢裂化工艺 潘海涛，高 歌，雷 振，陆江银 (新疆大学 化学化工学院 石油天然气精细化工教育部重点实验室，新疆 乌鲁木齐 830046) [摘要]以Y—AI：O，为载体，通过浸渍法制备了Co—Mo／T—AI：0，催化剂，并用硫代硫酸铵对催化剂进行预硫化，在连续固定床 反应器上考察了反应温度、重时空速和Mo负载量对低温煤焦油加氢裂化性能的影响。采用XRD，NH 一TPD，H 一TPR等手段 对催化剂进行了表征，并对加氢裂化轻质油进行了密度、黏度、元素分析、馏程和FTIR等测试。实验结果表明，煤焦油经加 氢后，油品品质明显改善。在反应温度为450℃、重时空速为0．4～0．6 h～、Mo负载量(W)为10％～12％的优化条件下，加氢裂 化效果最为显著，轻质油(汽油馏分和柴油馏分)收率约为80％。煤焦油加氢裂化后，烯烃、芳烃和氧含量显著降低。 [关键词]煤焦油；加氢裂化；钴一钼～～氧化铝催化剂；预硫化 [文章编号]1000—8144(2014)05—0517—06 [中图分类号]TQ 523．6 [文献标志码]A Hydrocracking Process of Coal Tar over Co-Mo／V·AI203 Catalysts PanHaitao，Gao Ge，LeiZhen，LuJiangyin (Key Laboratory ofOilGas Fine Chemicals，Ministry ofEducafion，College ofChemistry and Chemical Engineering， Xinjiang University，Urumqi Xinjiang 830046，China) l Abstract j Co—Mo／7-A1203 catalysts were prepared by impregnation with丫一AI2O3 as support and presulfurized with(NH4)2S203．The catalysts were characterized by means of XRD，NH3一TPD and H2一TPR，and used in the hydrocracking of coal tar in a continuous flow fixed—bed reactor．The effects of temperature，WHSV and Mo loading on the hydrocracking were investigated．The products were characterized by means of FTIR and elemental analysis，and their density，kinematic viscosity and boiling range were measured．It is showed that the quality of the products was improved significantly， and the yield of light oil reached about 80％ under the conditi