从裂解C9馏分中分离环戊二烯和甲基环戊二烯的研究-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2013年第42卷第11期 PETR0CHEMICAL TECHN0LOGY ·1213· 从裂解C9馏分中分离环戊二烯和 甲基环戊二烯的研究 李爱元 ，施立钦 ，孙向东 ，王 斌 ，张慧波 (1．宁波职业技术学院 化工系，浙江 宁波 315800；2．浙江恒河石油化工股份有限公司，浙江 宁波 315023) [摘要]以裂解c 馏分为原料，采用解聚一蒸馏法、解聚一精馏法、解聚一精馏一分离法进行分离环戊二烯(CPD)和甲基环戊二 烯(MCPD)的实验。考察分离方法、操作条件对CPD和MCPD的纯度和收率的影响。实验结果表明，解聚．蒸馏法，只能获得 高纯度的CPD，纯度达99．8％(W)；解聚一精馏法，可以同时获得高纯度的CPD和中等纯度的MCPD，CPD纯度达99．2％(W)， MCPD纯度达46．1％(W)；解聚一精馏一分离法分离效果最好，CPD纯度达99．4％(W)，收率达92．6％(W)，且MCPD纯度达 93．7％(W)，MCPD收率达89．6％(W)。 [关键词]环戊二烯；甲基环戊二烯；裂解c熘分；分离 [文章编号]1000—8144(2013)l1—1213—05 [中图分类号]TQ 028 [文献标志码]A Separation of CyclOpentadiene and Methylcyclopentadiene from Cracking C9 Fraction LiAiyuan ，ShiLiqin ，SunXiangdong 一，WangBin ，ZhangHuibo (1．Department ofChemicalEngineering，NingboProfessional andTechnicalCollege，NingboZhejiang 315800，China 2．Zhejiang Henghe Petrochemical Co．，Ltd，Ningbo Zhejiang 315023，China) [Abstract]Cyclopentadiene(CPD)and methylcyclopentadiene(MCPD)were separated from cracking C9 fraction by three separation methods，namely depolymerization—distillation，depolymerization— rectification and depolymerization-rectification—monomer separation．The effects of the separation methods and operational conditions on the purity and yield of CPD and MCPD were investigated．The results showed that，only CPD could be obtained by the depolymerization—distillation and its purity could reach 99．8％(w)；when the depolymerization—rectification method was used，both CPD with high purity and MCPD with medium purity could be obtained，and their purities could reach 99．2％(w