添加剂对α-氧化铝载体性能的影晌-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2013年第42卷第8期 PETROCHEMICAL TECHNOL0GY ·849· 添加剂对 一氧化铝载体性能的影响 王 辉，李金兵，陈建设，张志祥 (中国石化 北京北化院燕山分院，北京 102500) [摘要]以三水氧化铝为前体，在前体混合物中加入一定量的黏结剂和不同含量的添加剂，通过挤压成型的方法制备c【一氧化 铝载体，利用添加剂受热分解释放气体的特点改善c【一氧化铝载体的性能，并以Ⅱ一氧化铝为载体制备了负载型银催化剂。采用 XRD、颗粒强度测定仪、压汞仪、TG—DTA等手段研究了添加剂及其加入量对c【一氧化铝载体晶型、抗压强度、孔结构、晶相 转变温度的影响，利用乙烯环氧化反应评价了银催化剂的性能。实验结果表明，添加剂能抑制焙烧过程中氧化铝颗粒间的烧 结团聚、改善d一氧化铝载体的抗压强度及其孔直径尺寸、改变氧化铝q相变温度、提高银催化剂的活性和选择性，通过改变 添加剂的含量可进一步优化c【一氧化铝载体和银催化剂的性能。 [关键词]cc一氧化铝载体；添加剂；银催化剂；乙烯；环氧化；环氧乙烷 [文章编号]l000—8144(2013)08—0849—05 l中图分类号]TQ 426．65 [文献标志码]A Effect of Additive on Properties of —Alumina Support WangHui，LiJinbing，ChenJianshe，ZhangZhixiang (SINOPEC Research Institute of Beijing Yanshan Petrochemical Co．Ltd．，Beijing 1 02500，China) [Abstract]cc—Alumina was synthesized from gibbsite precursor with binder and additive through extrusion process，and was used in preparing supported silver catalysts for the epoxidation of ethylene to ethylene oxide．The 0【一alumina was modified with gases released from the additive by its decomposition．The modified supports were characterized by means of XRD，strength analyzer， mercury penetration method and TG-DTA to investigate the effect of the additive dosage on their performance．The catalytic performances of silver catalysts supported on the supports were evaluated in a micro—reactor．The results show that the addition of the additive can effectively inhibit the aggregation of 0【一alumina particles．improve the strength of the supports，enlarge their pore diameter and change their phase transition temperature．So