稀土金属氧化物助剂对费托合成-Al2O3催化剂性能的影响-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 886· PETROCHEMICAL TECHN0L0GY 2014年第43卷 稀土金属氧化物助剂对费托合成 Co／7-AI203催化剂性能的影响 孙 燕，孙启文，刘继森，张宗森 (上海兖矿能源科技研发有限公司煤液化及煤化工国家重点实验室，上海201203) [摘要]在浆态床反应器中考察ZrO：，CeO ，La：O，助剂对费托合成Co／y—A1：O 催化剂性能的影响。实验结果表明，ZrO：助剂 的添加最有利于提高Co／7．A1，O 催化剂的活性和石蜡选择性；CeO 助剂的添加有利于提高重质烃产物中的柴油馏分含量； La 0 助剂的添加有利于减弱水煤气变换反应的程度。XRD，TPR，H 一TPD等表征结果显示，稀土金属氧化物助剂的加入改变 了Co17．A1，0 催化剂的还原温度并可提高还原度，使活性co组分在催化剂表面保持高分散度，改善H：在催化剂表面的吸附脱 附性能。 [关键词]稀土金属氧化物；费托合成；钴催化剂；浆态床 [文章编号]1000—8144(2014)08—0886—06 [中图分类号]TQ 426 [文献标志码]A Effect of Rare Earth Metal Oxides on Performances of Co -AI2O3 Catalysts for Fischer-Tropsch Synthesis Sun Yan Sun Qiwen，Liu Jisen，ZhangZongsen (Shanghai Yankuang Energy RD Co．，Ltd．，State Key Laboratory of Coal Liquefaction and Coal Chemical Technology Shanghai 201203，China) [Abstract]The effects of rare earth metal oxides，namely ZrO2，CeO2 and La2O3，on the performances of Co／7一AI2O3 catalysts for the Fishcer-Tropsch synthesis were investigated in a slurry bed reactor．The results indicated that ZrO2 was beneficial to increasing the catalytic activity,decreasing the methane selectivity and improving the paraffin selectivity．The addition of the CeO2 promoter could increase the selectivity to long chain hydrocarbons and favor the diesel oil yield．The addition of LazO3 could decrease the probability of water gas transformation reaction．All the catalysts were characterized by me