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2015高测验题——理综(化学部分)(天津卷)解析版(国外英文资料)
2015高考试题——理综(化学部分)(天津卷)解析版(国外英文资料)
2 moles of l-1ba (OH) 2 solution Ba2 + matter is 0.024 moles, OH -- 0.048 moles, and the reaction generates 0.022 moles.
Test points: the size of the chemical image, the salt hydrolysis, the ionic radius.
(18) the amygdala is an important intermediates, using A and B as raw materials to synthesize the F route of the amygdala.
(1) A formula for C2H2O3, can produce silver mirror reaction, with acid, contains A functional group name: _______, write A + B and C chemical reaction equations for __________________________.
(2) there is a strong and weak order in which the acid of OH is strong to the weak.
(3) E is produced by two molecules of C, which contain three six-membered rings, and the molecules of E are in a different chemical environment.
(4) D - F type of response is __________, 1 mol F under certain conditions and adequate solution of NaOH, consumption of NaOH amount of substance as the most: ________mol.
Write the structure of all the isomers of F that meet the following conditions
One is a monoacid compound, and there are only two substituents in the benzene ring, one of which is the hydroxyl group
(5) known:
A has A variety of synthetic methods, and in the box the example of A process flow diagram of A process flow chart from acetic acid synthesis A (other ingredients) is as follows:
(1) the aldehyde group, the carboxyl group
(2) 3, 3, 3, 3
Resolution
Test analysis: (1) the molecular formula of A is C2H2O3, which can be reacted by silver mirror and is acidic, A is HOCCOOH, and the functional group is the aldehyde group and the carboxylic group. According to the structure of C, B is A phenol, and the chemical reaction of A plus B to C is:. (2) the carboxylic acid is stronger than phenolic hydroxyl group, phenolic hydroxyl acid is better than alcohol hydroxyl, so the pecking order is: (3) (1) (2) (3) with hydroxyl and carboxyl in C, 2 C molecules can occur esterification reaction and can generate 3 examination site: isomers
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