2009年_电工钢表面耐高温绝缘无机涂层的制备和表征.pdfVIP

# 220 # 2009 , ( , 200237) :以磷酸和氢氧化铝为原料在90~ 100 e 合成二聚磷酸三氢铝, 将硅酸钠, 草酸按 一定比例 加入到二聚磷酸三氢铝溶液 制备成粘度为0. 16~ 0.2 Pa # s 的涂液用浸渍提拉法在清洗过的 电工钢表面涂覆, 自然干燥 12 h 后, 经退火炉在600 e 热处理 1 min 得到耐高温绝缘涂层用X 射线衍射分析( XRD) 差热分析( DTA) 热重分析( T G) 及显微镜研究了涂层组成变化用 Franklin 烧损试验表征了涂层的绝缘能力结果表明,磷酸和氢氧化铝比例为3.3B 1 时生成二聚 磷酸三氢铝产率最高, 性能最稳定硅酸钠的加入既可以加强涂层的结合力又可以改善涂液的分 散性螯合剂的加入使涂料稳定存放涂层在300 e 稳定使用最高使用温度可达600 e : 二聚磷酸三氢铝; 涂层;绝缘;螯合剂 :T 126.3 : A : 0367-6358(2009) 04-0220-04 Preparation and Characterization of Electric Resistant at High Temperatures Inorganic Coating for Electric Steel LI Chun-hua, JIANG Jian-hua (S chool of M aterials S cience and E ngineer ing , E ast China Univ ersity of S cience and T ech nology , S hanghai 200237 , China) Abstract: AlH3( PO4)2 was synthesized at 90~ 100 e using phosphoric acid and aluminum hydroxide. A certain amount of sodium silicate and oxalic acid were added in to the AlH3 (PO4 )2 solution to make the viscosity of the solution of 0. 16~ 0.2 Pa # s. The film was prepared by dip-drag method, followed by 12 hours natural drying and 1min heating at 600 e . T he composition changes in the coating process were studied by XRD, DTA, T G and microscope. The insulation capability of the coating was tested by Franklin test. Experimental results showed that the products were stable and the yield reached maximum, when the proportion of H3PO4 and Al( OH)3 was 3.3B 1. T he addition of sodium silicate can guarantee the uniformity and fastness of the coating. T he chelating agent can prolong the stable time of the solution. The coating can be used for long-term under 300 e . T he maximum usable temperature will be up to 600 e . Key words: AlH3( PO4)2 ; coating; r