W-SBA-15催化环氧化苯乙烯合成环氧苯乙烷.pdfVIP

27 3 2010 5 SPECIALITY PETROCHEMICALS 15 WSBA15 * (, 113001) : Na WO WSBA15 , XRDBET WSBA15 2 4 30%H O , ,WSBA15 2 2 :70 , 8 h, 10. 0%( ) ,n ( ) : n( ) : n(H O ) = 1 2 2, 34.25%, 36. 54%, 2 2 12.51%( ) : WSBA15 :T 426.94 : A , igaku D/ MAX1AX , Cu [ 1, 2] UV , K ,100 mA, 40 kV; Microme ritics ASAP 2010 ,N2 , 77 K, 383 K 16 [3] , h; HP4890 , , , , , , ,50 m ! 0. 125 mm , , 170 , 1 min, 3 , / min 220 , , , 1. 2 , [ 8] Na2 WO4 W [4] SBA15 , Si/ W ( ) 2432 [5~ 7] 4795 WSBA15 , [ 8] Na2 WO4 H2WO4 BCDE, SBA15 A WSBA15 , 1. 3 [9] 2 2 W H O : : PhCH CH + H O PhC H O SBA15 , 2 2 2 2 3 ,PhC2H3O 1 , 1. 1 : PhCH CH + H O PhCHO P123( EO20 PO70 EO20 , 2 2 2