乳化和润湿反转现象的耗散粒子动力学研究.pdfVIP

3 0 　 2 Vol.3 0 No.2 　 2 009 3 ACTA PET ROLEI SINICA Mar. 　 2 00 9 :0253-2697 (2 00 9)02-0259-04 1 1 2 3 李小波 　刘曰武 　李树皎 　唐剑斐 (1. 　　100190;　2.　　100101; 3.　　100101) :利用耗散粒子动力学方法, 研究了化学驱过程中乳化和润湿反转两 个重要的物 化学现象。 通过合 划分流体粒子和定义 粒子之间相互作用参数, 模拟了十二烷基苯磺酸钠、正十二烷和水三组分体系的自发乳化现象;通过附加固壁条件, 模拟了在水动 力作用下吸附在岩石表面的油珠发生破裂的非自发乳化过程, 以及由于表面活性剂在岩石表面吸附而引起的润湿反转现象, 比较 了润湿反转前后残余油珠的运动情况。 模拟结果表明:作为介观力学的离散粒子动力学方法, 耗散粒子动力学方法可作为研究包 含物 化学现象的化学驱渗流问题的重要手段。 :强化采油;化学驱;乳化;润湿反转;耗散粒子动力学;介观力学 :TE3 57 　　　　:A Simulation of emulsification and wettability alteration phenomena with dissipative particle dynamics 1 1 2 3 LI Xiaobo 　LIU Yue u 　LI Shujiao 　TANG Jianfei (1.Dep artment of Engineering Sciences in the Institute of Mechanics, Chinese Academy of Sciences, Beij ing 10 0190, China;　2 .CNPC Great Wall Drilling Comp any, Beij ing 100 10 1, China; 3. op well Service Comp any , Ltd., Beij ing 10 0101, China) Abstract:The dissipative particle dynamics (DPD) as used to simulate the emulsification and ettability alteration phenomena in the process of chemical flooding.The spontaneous emulsifications of sodium dodecylbenzene sulfate (SDBS), dodecane and three- component ater system ere simulated on the basis of the reasonable selection of particles and definition of interaction parameters bet een particles.The solid all boundary conditions ere adopted to simulate the non-spontaneous emulsification process of oil drop remained on the surface of rock under the action of hydrodynamics.The ettability alteration phenomena induced by the ad- so