煤焦与生物质焦CO_2共气化特性及分布活化能研究.pdf

第 31 卷 第 8 期 中 国 电 机 工 程 学 报 Vol.31 No.8 Mar.15, 2011 2011 年 3 月 15 日 Proceedings of the CSEE ©2011 Chin.Soc.for Elec.Eng. 51 文章编号：0258-8013 (2011) 08-0051-07 中图分类号：TK 122 文献标志码：A 学科分类号：470·10 煤焦与生物质焦 CO 共气化特性 2 及分布活化能研究 高正阳，胡佳琪，郭振，王星久，吴小芳 ( 电站设备状态监测与控制教育部重点实验室(华北电力大学) ，河北省 保定市 071003) Investigation on the Co-gasification of Coal Char With Biomass Char and the Distributed Activation Energy GAO Zhengyang, HU Jiaqi, GUO Zhen, WANG Xingjiu, WU Xiaofang (Key Laboratory of Condition Monitoring and Control for Power Plant Equipment (North China Electric Power University), Ministry of Education, Baoding 071003, Hebei Province, China) ABSTRACT: Thermo gravimetric analyzer (TGA) 的分布活化能进行了计算与分析。研究结果表明：煤焦、 experiments for gasification of sawdust char, wheat straw char 秸秆焦、木屑焦 3 种焦样中煤焦的反应性显然较差；对于 and coal char and co-gasification of their mixtures in CO2 煤焦和秸秆焦，Na 盐的催化效果优于 Ca 盐；对于木屑焦， atmosphere were conducted. Characteristics of the gasification Ca 盐的催化效果更显著。Na 盐与 Ca 盐的添加均可使秸秆 with and without catalysts were investigated. Kinetics of char 焦气化反应速率显著增加，但反应所需温度的下降却不显 gasification was studied employing distributed activation 著。在木屑焦中添加 Na 盐与 Ca 盐后，气化反应所需温度 energy model (DAEM). Experimental data indicate that coal 的下降比秸秆焦显著。对于煤焦，添加催化剂首先使气化 char is apparently less active among these three kinds of char. 所需温度显著下降，反应速率并不显著增加；但进一步增 And catalytic effect of Na salts on the gasification of coal char 加催化剂，则主要使反应速率提高，反应所需温度不再显 or straw char is greater than Ca slats while Ca salts function as 著下降。在反应过程中，各样品的分布活化能均表现出先 better catalysts to the gasification of sawd