电沉积镍纳米晶材料制备及性能.pdf

第23 卷 第3 期 电镀 与 涂 饰 Vol. 23 No. 3 2004 年6 月 Electroplating Finish ing Jun. 2004 =研究报告 王立平, 高燕, 薛群基, 刘惠文, 徐洮 ( 中国科学院兰州化学物理研究所固体润滑国家重点实验室, 甘肃 兰州 730000) : 采用直流电沉积法向镀液中加入复合有机 加剂制备了镍纳米晶材料。采用扫描电镜及X 射线衍射 仪分析了该纳米晶材料的微观形貌及相结构。测定了其结合强度、显微硬度及耐磨性能。结果表明, 该纳米镍镀层表 面致密、平整, 且结合强度、显微硬度及耐磨性能优良, 与粗晶镍镀层相比有较大的提高。 : 电沉积; 镍纳米晶; 复合有机 加剂 : TQ153112 : A : 1004- 227X( 2004) 03- 0001- 02 Properties and preparation of eletrodeposited nanocrystalline nickel films WANG Li2ping, GAO Yan, XUE Qun2 i, LIU Hu i2wen, XU Tao ( State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences , Lanzhou 730000, China) Abstract: Eletrodeposited nanocrystalline nickel films were obtained with addition of compound organic additives in the solution and with direct current. The morphology and crystal structure of the nanocrystalline nickel film were analyzed with SEM and X2ray diffraction instruments. The adhension, micro2hardness and abrasive resistance of the film were test2 ed. Results show that the nanocrystalline nickel film obtained has fine and leveled surface and satisfactory propert ies ment ioned above which are greatly improved compared with those of macrocrystalline nickel films. Keywords: eletrodeposition; nanocrystalline nickel film; compound organic additive 性能系统的研究较少。本文采用直流电沉积技术制备 1 了镍纳米晶材料, 并对其微观结构、力学和摩擦学性能 纳米材料因自身具有小尺寸效应、量子效应、