固相配位反应及配合物性质表征剖析.docx

固相配位反应及配合物性质表征摘要：本实验研究的是固相反应和固相化合物的表征，在室温下将8-羟基喹啉与四水合乙酸钴（物质的量比2：1），在研钵中充分研磨，发生固相配位反应。用元素分析、IR、TG-DTA对产物进行表征其测定结果表明：配合物的反应级数n=3，活化能Ea=359.32kJ/mol,频率因子k0=9.297×1022，速率系数k=1.509×10-3s-1，并有四个未成对电子。关键词：8-羟基喹啉，四水合乙酸钴，固相配位反应，表征Abstract:This study is the solid-phase reaction and solid-phase compounds were characterized at room temperature will be eight-hydroxyquinoline in acetic acid according to the molar ratio of 2:1 Cobalt(II) Acetate Tetrahydrate -accurate weighing, grinding in a mortar fully occurred solid-solid state reaction. Mixture after the end of the color change, and to purify the complex