不同阻化剂对煤自燃临界温度影响的实验研究 .pdfVIP

学兔兔 煤 炭 工 程 2012年第2期 不同阻化剂对煤自燃临界温度影响的 实验研究 焦新明1,2，王德明1,2，仲晓星 ，李金帅 ，雷 丹 (1．中国矿业大学安全工程学院，江苏徐州 221008； 2．中国矿业大学煤炭资源与安全开采国家重点实验室，江苏徐州 221008) 摘 要：采用水玻璃、CaC1，、凝胶三种阻化剂对湖西褐煤、大佛寺不粘煤、袁庄气肥煤、 新丰贫煤四种不同变质程度煤样进行处理后，测试其在程序升温条件下40～180℃范围内CO的 浓度，并计算临界温度。结果表明经阻化剂处理后的煤样，临界温度均发生了不同程度的升高， 其中经CaC1 处理后的煤样临界温度最高，说明CaC1 阻化剂能更有效地抑制活性官能团较早的 参与化学反应，从而延缓煤的氧化。 关键词：阻化剂；临界温度；CO浓度；自燃 中图分类号：TD75 文献标识码：B 文章编号：1671—0959(2012)02-0088-04 Experiment Study on Different Retarder Affected to Critical Temperature of Coal Spontaneous Combustion JIAO Xin—ruing ，WANG De—ruing ，ZHONG Xiao—xing ，LI Jin—shuai ，LEI Dan ’ (1．School of Safety Engineering，China University of Mining and Technology，Xuzhou 221008，China； 2．National Key Lab of Coal Resources and Safety Mining，China University of Mining and Technology，Xuzhou 221008，China) Abstract：After three retarders of sodium silicate，CaC12 and gel were applied to treat four different metamorphism degree coal samples of Huxi lignite，Dafosi non—caking coal，Yuanzhuang gas—fat coal and Xinfeng meager coa1．The CO concentration within 40～18012 under the condition of the programmed temperature rising was measured and the critical temperature was calculated．The results showed that after the treatment with the retarders，the critical temperatures of the coal samples all had a temperature rising in different degree．Among the coal samples，the coal sample treated with CaC1 2，the critical temperature would be the highest． Thus the CaC12 retarder could effectively control the activa