金属参与的水相烯丙基化反应.pdfVIP

第 19 卷 第 6 期 化　学　进　展 Vol. 19 No. 6 2007 年 6 月 PROGRESS IN CHEMISTRY 　June , 2007 金属参与的水相烯丙基化反应 1 ,2 1 1 ,2 1 谢　斌 　冯建申 　邹立科 　张秀兰 ( 1. 四川理工学院化学系 　自贡 643000 ; 2. 四川理工学院绿色化学院级重点实验室 　自贡 643000) 摘 　要 　近 30 年来 ,水介质中碳碳键的形成一直是研究的热点 ,其优越性也逐渐被人们所认知。在已 发现的水相金属有机反应中 ,水相烯丙基化反应是研究得较多和较深入的反应之一。水相烯丙基化反应由 于其发展速度较快 ,新的金属及金属体系参与的烯丙基化反应 , 以及水相烯丙基化反应的机理研究不断被报 道。本文综述了水相中金属参与的烯丙基化反应的最新研究进展 ,并对新的反应机理作了简要的阐述。 关键词 　绿色化学 　水相 　金属参与 　烯丙基化 ( ) 中图分类号: O62125 　文献标识码 : A 　文章编号 : 1005281X 2007 Allylation Reaction Mediated by Metals in Aqueous Media 1 ,2 1 1 ,2 1 Xie Bin 　Feng Jianshen 　Zou Like 　Zhang Xiulan ( 1. Department of Chemistry , Sichuan University of Science Engineering , Zigong 643000 ,China ; 2. Key Laboratory of Green Chemistry , Sichuan University of Science Engineering , Zigong 643000 , China) Abstract 　The formation of carboncarbon bond in aqueous media has been the focus of research in recent three decades , and its advantages are gradually recognized. Aqueous allylation reaction mediated by metals is one of the most widely researched organometallic reactions in aqueous media. Because of the rapid development of allylation reaction in aqueous media , allylation reaction mediated by new metals or metal systems , and its mechanism are reported increasingly. This article summarizes the latest research progress of the allylation reaction mediated by metals in aqueous media , and the new reaction mechanism is explained briefly.