理优双语2006-2007学年第一学期B卷.docVIP

华东理工大学2006–2007学年第一学期 《 有机化学 》课程期末考试试卷 B 2007.2.26 开课学院：理优05 专业： 考试形式：一页开卷，所需时间：120分钟 考生姓名： 学号： 班级： 任课教师：荣国斌 题序 一 二 三 四 五 六 七 八 总 分 得分 ? ? ? ? ? ? ? ? ? 评卷人 ? ? ? ? ? ? ? ? ? ? 可用中文或英文回答一~七各题（共六页，八大题）： ? 一. (1) Write the structure of all the alkenes that can be hydrogenated to form 2-methylpentane.(6 points) ? ? ? ? ? ? ? ? ? (2) Assign E/Z configurations to each of the following alkenes: (4 points) ? ? ? ? ? ? ? ? ? (3) Assign R and S designation to the following compounds: (4 points) ? ? ? ? (4) Place the following radicals in decreasing order of stability: (4 points) CH3CH2·C(CH3)2 ·CH2CH2CH(CH3)2 CH3·CHCH(CH3)2 1 2 3 ? ? ? ? (5) For each of the following compounds,give the number of H’s with distinct NMR signals,and their relative δ values in decreasing order. (6 points) CaH3OC(CbH3)3 CaH3CbH2CO2cH 1 2 ? ? ? 二． (1) Give the product from the hydroboration-oxidation of 1-methylcyclopentene and classify the mode of addition.(6 points) ? ? ? ? ? (2) Give the structures of the products of the following reactions:(4 points) ? ? ? ? (3) Write the structure for the products from reductive ozonolysis of 1,2-dimethylcyclohexene. (2points) ? ? ? ? ? ? (4) Prepare (a) PhCHDCH3 (b) p-DC6H4CH2CH3 from PhCH2CH3. (8 points) ? ? ? ? ? ? ? ? ? ? 三. Account for the formation of both 2-bromo-3,3-dimethylbutane and 2-bromo-2,3-dimethylbutane from the reaction of HBr with 3,3-dimethyl-1-butene.(10 points) ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? 四. The synthetic sequences shown below are unlikely to occur as written. Tell what is wrong with each, and predict the true product: (6 points) （1） ? ? ? （2） ? ? ? 五. Indicate the products in each following transformation case. (10 points) (1) (2) (3) (4) (5) ? 六. Using acetylene and any alkyl halides as starting materials, synthesize the following compounds 1 and 2 respectively. More