气体分析仪的原理与应用-Servomax.ppt

样气中的氧气总是设法使得哑铃偏转 高精度的反馈回路阻碍哑铃的旋转,给出氧浓度的直接测量值 仕富梅磁氧技术用于 ........ 氧分析的原理 电化学式 顺磁性 氧的顺磁性 Unpaired electrons align with a magnetic field and behave like small magnets Oxygen molecules are attracted into a magnetic field NB - Thermal agitation knocks electrons out of alignment and reduces magnetic susceptibility 磁氧传感器的类型 Magneto-dynamic (Servomex) 热/磁风 Quinke cell 磁风 磁风测量室的特点 热装置容易受到背景气体的导热系数影响 Temperature sensitive Tilt and flow sensitive Pressure sensitive (effect = 1:1.5) Combustibles may burn on filament causing errors 普通的灵敏度 Quinke cell Quinke cell features Constant flow of nitrogen reference gas required Poor sample pressure sensitivity - effect of changes = 2:1 Suitable for very corrosive gases Not affected by sample thermal conductivity Servomex paramagnetic cell Servomex null balance system Magneto-dynamic cell Null balance system - extremely linear Fast response, low pressure effect (1:1) Very high resolution Temperature compensated Corrosion resistant materials Not sensitive to thermal conductivity of background gases Extremely long life - does not fail “unsafe” Servomex cell features Effect of background gases small Operates up to 110C (with 1100H) Effect of pressure (1:1) is easily compensated Solvent resistant version available (364N cell) Flammable samples can be handled (ia) electronics Servomex Infrared cell(Single Beam, Dual Wavelength - SBDW) Dual Beam IR Sensors Drift results from Measurement cell contamination. Ageing detector, mechanical movement Servomex Gfx(Gas Filter Correlation) Servomex Gas Filter Correlation (Gfx) Servomex Gfx(Gas Filter Correlation) Servomex Gfx(Gas Filter Correlation) Gas Filter Correlation How It Works Uses a gas filter to produce a beam which has already selectively absorbed IR energy absorbed by the gas to be measured, referenced to a beam which has not. Infrared Absorption Like many other pollutant gases, CO absorbs electromagnetic radiation in the infrared spectrum. The amount of energy absorbed provides